Crystallographic isomorphism (S,Tl) in the structure of TlHg6S4Br5

被引：0
|
作者：
S. V. Borisov
S. A. Magarill
N. V. Pervukhina
机构：
[1] Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry, Siberian Branch
来源：
Journal of Structural Chemistry | 2015年 / 56卷
关键词：
crystallographic analysis; mercury chalcogenides; isomorphism (S, Tl); Tl; anion site;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Crystallographic analysis of the known structure of TlHg6S4Br5 reveals that the Tl+ cation occupies the S2-site, centering the cubic Br subcells in the unit cell. The analysis shows that Tl is located in one sublattice with Br and S anions, and the Hg cationic sublattice, which has a relatively small size and large amount of vacant sites, is coordinated with the anionic one due to the selective site occupation in the former. An algorithm is considered for calculating the compositions with a given proportion of large monovalent cations substituting for S.
引用
下载
收藏
页码：1183 / 1187
页数：4
相关论文
共 50 条
  • [31] SYNTHESIS AND CRYSTAL-STRUCTURE OF K4AU6S5, A THIOAURATE WITH ANIONIC [AU6S5] GROUPS
    KLEPP, KO
    BRONGER, W
    JOURNAL OF THE LESS-COMMON METALS, 1988, 137 (1-2): : 13 - 20
  • [32] Isomery of [Re6S6Br8] and [Re6S5Br9] Units in a Rhenium Cluster Thiobromide: Experimental and Theoretical Approaches
    Bruno Fontaine
    Régis Gautier
    Guillaume Pilet
    Stéphane Cordier
    Christiane Perrin
    André Perrin
    Yuri V. Mironov
    Journal of Cluster Science, 2009, 20 : 145 - 151
  • [33] CRYSTAL STRUCTURE OF HUTCHINSONITE (TL,PB)2AS5S9
    TAKEUCHI, Y
    GHOSE, S
    NOWACKI, W
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1965, 121 (05): : 321 - &
  • [34] CRYSTAL-STRUCTURE OF THALLIUM SULFIDE, TL2S5
    LECLERC, B
    KABRE, TS
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1975, 31 (JUN15): : 1675 - 1677
  • [35] Isomery of [Re6S6Br8] and [Re6S5Br9] Units in a Rhenium Cluster Thiobromide: Experimental and Theoretical Approaches
    Fontaine, Bruno
    Gautier, Regis
    Pilet, Guillaume
    Cordier, Stephane
    Perrin, Christiane
    Perrin, Andre
    Mironov, Yuri V.
    JOURNAL OF CLUSTER SCIENCE, 2009, 20 (01) : 145 - 151
  • [36] SYNTHESIS AND CRYSTAL-STRUCTURE OF BR5+ASF6-, BR5+SBF6-
    HARTL, H
    NOWICKI, J
    MINKWITZ, R
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (03): : 328 - 329
  • [37] PHASE-DIAGRAMS OF THE SECTIONS AS2S3-TL3ASS4, TL3ASS4-S, AND TL3ASS4-TL2S OF THE TERNARY-SYSTEM AS-TL-S
    VOROBEV, YI
    VELIKOVA, NG
    KIRILENKO, VV
    SHCHELOKOV, RN
    INORGANIC MATERIALS, 1987, 23 (07) : 996 - 1001
  • [38] STRUCTURE OF (4S,5R)-6-BROMO-6-DEOXYASCORBIC ACID
    RUZICTOROS, Z
    KOJICPRODIC, B
    HORVATIC, D
    SUSKOVIC, B
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1989, 45 : 269 - 273
  • [39] Molecular octahedral sulfido-bromide rhenium clusters: Synthesis and crystal structure of (PPh(4))(2)[Re6S6Br8]center dot CH3C6H5 and (PPh(4))(3)[Re6S7Br7]
    Fedin, VP
    Imoto, H
    Saito, T
    Fedorov, VE
    Mironov, YV
    Yarovoi, SS
    POLYHEDRON, 1996, 15 (08) : 1229 - 1233
  • [40] OXIDATIVE TRANSFORMATION OF THE [FE4S4X4]2- CUBANES TO THE [FE6S6X6]2- PRISMANE CLUSTERS (X = CL, BR) - THE CRYSTAL AND MOLECULAR-STRUCTURE OF [(C6H5)4P]2FE6S6CL6
    COUCOUVANIS, D
    KANATZIDIS, MG
    DUNHAM, WR
    HAGEN, WR
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (25) : 7998 - 7999
12345