Synthesis and physico-chemical characterization of new dithiocarabamato ligand and its complexes with copper(II), nickel(II) and palladium(II)

被引：0

作者：

Z. B. Leka

V. M. Leovac

S. Lukić

T. J. Sabo

S. R. Trifunović

K. M. Szécsényi

机构：

[1] University of Montenegro,Faculty of Metallurgy and Technology

[2] Institute of Chemistry,University of Novi Sad, Faculty of Sciences

[3] Institute of Physics,University of Novi Sad, Faculty of Sciences

[4] University of Belgrade,Faculty of Chemistry

[5] Institute of Chemistry,University of Kragujevac, Faculty of Sciences

来源：

Journal of Thermal Analysis and Calorimetry | 2006年 / 83卷

关键词：

copper(II) complexes; IR; nickel(II) complexes; palladium(II) complexes; thermal analysis; triammonium-N-dithiocarboxyiminodiacetate; UV/VIS-spectrometry;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Triammonium-N-dithiocarboxyiminodiacetate, (NH4)3L, a new dithiocarbamato derivative of iminodiacetate, has been synthesized. The coordination properties of the ligand were tested in reactions with copper(II), nickel(II) and palladium(II) salts in acidic solutions. Complexes with a general formula M(H2L)2 were obtained, with the coordination taking place through the sulfur atoms of the dithiocarbamate moiety. The new compounds were characterized by elemental analysis, UV/VIS and IR spectroscopy, thermal analysis and magnetic measurements. In addition, the ligand was characterized by 1H- and 13C-NMR spectroscopy and molar conductivity measurements. The copper(II) complex is paramagnetic, while the nickel(II) and palladium(II) compounds are diamagnetic. The thermal decomposition of all compounds is continuous and the thermal stability of the complexes is higher than that of the ligand, as expected.

引用

页码：687 / 691

页数：4

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