Kinetic aspects of [3+2] cycloaddition reactions between (E)-3,3,3-trichloro-1-nitroprop-1-ene and ketonitrones

被引：0
|
作者：
Radomir Jasiński
Kamila Mróz
机构：
[1] Cracow University of Technology,Institute of Organic Chemistry and Technology
来源：
Reaction Kinetics, Mechanisms and Catalysis | 2015年 / 116卷
关键词：
1,3-Dipolar cycloaddition; Nitrone; Nitroalkene; Solvent effect;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Kinetic measurements show that despite their polar nature, cycloaddition reactions of (E)-3,3,3-trichloro-1-nitroprop-1-ene with ketonitrones take place according to a mechanism that proceeds without intervention of zwitterionic intermediate. This is indicated by the values of activation parameters (activation enthalpy, activation entropy) and the nature of the kinetic solvent effect.
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页码：35 / 41
页数：6
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