Kinetic aspects of [3+2] cycloaddition reactions between (E)-3,3,3-trichloro-1-nitroprop-1-ene and ketonitrones

被引：0

作者：

Radomir Jasiński

Kamila Mróz

机构：

[1] Cracow University of Technology,Institute of Organic Chemistry and Technology

来源：

Reaction Kinetics, Mechanisms and Catalysis | 2015年 / 116卷

关键词：

1,3-Dipolar cycloaddition; Nitrone; Nitroalkene; Solvent effect;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Kinetic measurements show that despite their polar nature, cycloaddition reactions of (E)-3,3,3-trichloro-1-nitroprop-1-ene with ketonitrones take place according to a mechanism that proceeds without intervention of zwitterionic intermediate. This is indicated by the values of activation parameters (activation enthalpy, activation entropy) and the nature of the kinetic solvent effect.

引用

页码：35 / 41

页数：6

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