Pyridine-type complexes of transition-metal halides

被引:0
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作者
K. Mészáros Szécsényi
T. Wadsten
A. Kovács
G. Liptay
机构
[1] University of Novi Sad,Department of Chemistry, Faculty of Sciences
[2] Budapest University of Technology and Economics,Department of Inorganic Chemistry
[3] Budapest University of Technology and Economics,Research Group of Technical Analytical Chemistry of the Hungarian Academy of Sciences at the Institute of General and Analytical Chemistry
关键词
host-guest phenomenon; FT-IR spectrometry; manganese(II) chloride-lutidine (dimethylpyridine) complexes;
D O I
10.1023/B:JTAN.0000027190.32572.8b
中图分类号
学科分类号
摘要
Manganese(II) chloride complexes with 3,4- and 3,5-lutidine have been prepared. The crystal symmetry and cell dimensions have been calculated on the basis of powder diffraction data. The compounds were characterised also by FT-IR spectrometry. The thermal decomposition of the complexes has been studied by thermogravimetry and DSC. By plotting densities vs. molar mass, the diagram obtained has correspondence to similar observations in other solid metal-lutidine complex systems.
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页码:965 / 974
页数:9
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