N(II) oxide coordination to Co complexes with water-soluble porphyrin

被引：0
|
作者：
S. G. Pukhovskaya
L. Zh. Guseva
S. V. Makarov
A. S. Semeikin
O. A. Golubchikov
机构：
[1] Russian Academy of Sciences,Institute of Solution Chemistry
[2] Ivanovo State University of Chemical Technology,undefined
来源：
Russian Journal of Coordination Chemistry | 2006年 / 32卷
关键词：
Porphyrin; Coordination Chemistry; Electronic Absorption Spectrum; Nitrosyl; Nitrosyl Complex;
D O I：
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中图分类号：
学科分类号：
摘要：
Novel, water-soluble metalloporphyrin of zwitterionic type (Co complex with 5,10,15,20-tetra(4N-carboxymethylenepyridyl)porphyrin tetrabromide) was synthesized and its interaction with N(II) oxide was studied. IR and electronic absorption spectra were analyzed. Alcoholic solutions of this complex saturated with NO were found to contain all three types of coordinated ligands, i.e., NO, NO+, and NO−.
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页码：563 / 566
页数：3
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