Thermodynamic prediction of interfacial tension of water/oil system with the presence surfactants and salt

被引:0
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作者
Saber Nikseresht
Farshad Farshchi Tabrizi
Masoud Riazi
Farshid Torabi
Seyed Hossein Hashemi
机构
[1] Shiraz University,Department of Chemical Engineering, School of Chemical and Petroleum Engineering
[2] Shiraz University,Enhanced Oil Recovery Research Center, School of Chemical and Petroleum Engineering
[3] University of Regina,Petroleum Systems Engineering, Faculty of Engineering and Applied Science
[4] University of Mohaghegh Ardabili,Msc Chemical Engineering
[5] Islamic Azad University,Young Researchers and Elite Club, Shiraz Branch
关键词
Interfacial tension; Ionic surfactant; Salt; Extended UNIQUAC model;
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摘要
In this paper, a modified thermodynamic equation to predict interfacial tension (IFT) at oil/water interfaces with the presence of ionic surfactants and salt is considered. The surfactant activity coefficient is optimized based on the Extended UNIQUAC model according to the experimental results and is used in the modified model. In this study, the effect of salt with the presence of surfactants such as DTAB, M12 L12, SDBS and PFSA in the water/oil system has been considered to investigate the interfacial tension. According to the results of this study, the proposed equation can present a reasonable description of oil/water IFT measurements in the presence of cationic or anionic surfactant solutions and in a range of added salt.
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页码:2193 / 2199
页数:6
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