Thermodynamic prediction of interfacial tension of water/oil system with the presence surfactants and salt

被引:3
|
作者
Nikseresht, Saber [1 ]
Farshchi Tabrizi, Farshad [1 ]
Riazi, Masoud [2 ]
Torabi, Farshid [3 ]
Hashemi, Seyed Hossein [4 ,5 ]
机构
[1] Shiraz Univ, Sch Chem & Petr Engn, Dept Chem Engn, Shiraz, Iran
[2] Shiraz Univ, Sch Chem & Petr Engn, Enhanced Oil Recovery Res Ctr, Shiraz, Iran
[3] Univ Regina, Fac Engn & Appl Sci, Petr Syst Engn, Regina, SK S4S 0A2, Canada
[4] Univ Mohaghegh Ardabili, Msc Chem Engn, Ardebil, Iran
[5] Islamic Azad Univ, Young Researchers & Elite Club, Shiraz Branch, Shiraz, Iran
关键词
Interfacial tension; Ionic surfactant; Salt; Extended UNIQUAC model; ADSORPTION; EQUATION;
D O I
10.1007/s40808-021-01217-1
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In this paper, a modified thermodynamic equation to predict interfacial tension (IFT) at oil/water interfaces with the presence of ionic surfactants and salt is considered. The surfactant activity coefficient is optimized based on the Extended UNIQUAC model according to the experimental results and is used in the modified model. In this study, the effect of salt with the presence of surfactants such as DTAB, M12 L12, SDBS and PFSA in the water/oil system has been considered to investigate the interfacial tension. According to the results of this study, the proposed equation can present a reasonable description of oil/water IFT measurements in the presence of cationic or anionic surfactant solutions and in a range of added salt.
引用
收藏
页码:2193 / 2199
页数:7
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