Synthesis, spectral, thermal, and a crystalline structure of complexes containing [MeC(CH2PPh2)3Cu(I)]

被引：0
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作者：
Ismail Warad
Omar H Abd-Elkader
Ahmed Boshaala
Nabil Al-Zaqri
Belkheir Hammouti
Taibi Ben Hadda
机构：
[1] King Saud University,Department of Chemistry, Science College
[2] King Saud University,Electron Microscope Unit, Zoology Department, College of Science
[3] Benghazi University,Chemistry Department, Faculty of Science
[4] Université Mohammed 1er,LCAE
[5] Université Mohammed 1er,URAC18, Faculté des Sciences
来源：
Research on Chemical Intermediates | 2013年 / 39卷
关键词：
Cu(I) complexes; Tripodal phosphine ligands; Crystal structure; NMR;
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摘要：
The preparation of new [MeC(CH2PPh2)3CuCl] 1 and its derivatives was carried out directly by mixing of CuCl and MeC(CH2PPh2)3 ligand in dry THF, the neutral precursor 1 served to prepare [MeC(CH2PPh2)3Cu(NCCH3)]BF42 and [MeC(CH2PPh2)3Cu(PCH2Ph)3]BF43. These complexes are characterized on the basis of elemental analysis, IR, EDS, 1H, 13C and 31P{1H}NMR, FAB-MS, TG/DTA and single-crystal X-ray diffraction studies. Complex 1 crystallizes in the Orthorhombic unit cells with the space group Pna2(1). The structural behavior of MeC(CH2PPh2)3 ligand in the formed complexes during the coordination reaction was monitored by 31P{1H}NMR in CDCl3 at room temperature for the first time.
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页码：721 / 732
页数：11
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