Phase Equilibria in the SrS—In2S3 System

被引：0
|
作者：
A. V. Kertman
机构：
[1] Tyumen State University,
来源：
Russian Journal of Inorganic Chemistry | 2019年 / 64卷
关键词：
sulfides AIn; S; (A is alkaline-earth metal); phase diagram; eutectic; solid solution;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
It was determined that the SrS—In2S3 system is of the eutectic type with the incongruently melting compound SrIn2S4 and limited regions of solid solutions based on polymorphic modifications of In2S3. The compound SrIn2S4 crystallizes in the orthorhombic system (space group Fddd) with the unit cell parameters a = 2.090 nm, b = 2.113 nm, and c = 1.302 nm. The incongruent melting point of SrIn2S4 is 1220 K, and its microhardness is H = 2650 MPa. The composition and melting point of the eutectic are 73 mol % In2S3 and 1170 K, respectively. The solubility of SrS in α-In2S3 at 1070 K reaches 6 mol % SrS.
引用
收藏
页码：130 / 134
页数：4
相关论文
共 50 条
  • [41] PHASE-EQUILIBRIA IN CAS-GD2S3-GDS SYSTEM
    ANDREEV, OV
    KISLOVSKAYA, TM
    IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA I KHIMICHESKAYA TEKHNOLOGIYA, 1991, 34 (02): : 119 - 121
  • [42] PHASE-EQUILIBRIA IN SRS-LN2S3 SYSTEMS, WHERE (LN=LA, LN=ND, LN=GD)
    ANDREEV, OV
    KERTMAN, AV
    BAMBUROV, VG
    ZHURNAL NEORGANICHESKOI KHIMII, 1991, 36 (01): : 253 - 256
  • [43] Unraveling the Growth Mechanism Forming Stable γ-In2S3 and β-In2S3 Colloidal Nanoplatelets
    Horani, Faris
    Lifshitz, Efrat
    CHEMISTRY OF MATERIALS, 2019, 31 (05) : 1784 - 1793
  • [44] Phase equilibria in the Cu2S–Cu3AsS4–S system
    Z. T. Gasanova
    L. F. Mashadieva
    Yu. A. Yusibov
    M. B. Babanly
    Russian Journal of Inorganic Chemistry, 2017, 62 : 591 - 597
  • [45] Phase equilibria in the In2O3-WO3 system
    Richard, AP
    Edwards, DD
    SOLID STATE IONICS-2002, 2003, 756 : 199 - 204
  • [46] Phase equilibria in the Cu-Cu2S-As system
    Gasanova, Z. T.
    Aliev, Z. S.
    Yusibov, Yu. A.
    Babanly, M. B.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2012, 57 (08) : 1158 - 1162
  • [47] Phase equilibria in the Cu-Cu2S-As system
    Z. T. Gasanova
    Z. S. Aliev
    Yu. A. Yusibov
    M. B. Babanly
    Russian Journal of Inorganic Chemistry, 2012, 57 : 1158 - 1162
  • [48] SYNTHESIS AND PHOTOELECTROCHEMISTRY OF IN2S3
    BECKER, RS
    ZHENG, T
    ELTON, J
    SAEKI, M
    SOLAR ENERGY MATERIALS, 1986, 13 (02): : 97 - 107
  • [49] Structure reinvestigation of α-, β- and γ-In2S3
    Pistor, Paul
    Merino Alvarez, Jose M.
    Leon, Maximo
    di Michiel, Marco
    Schorr, Susan
    Klenk, Reiner
    Lehmann, Sebastian
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2016, 72 : 410 - 415
  • [50] PHASE EQUILIBRIA IN THE SYSTEM BATIO3-SIO2
    RASE, DE
    ROY, R
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1955, 38 (11) : 389 - 395
12345