Peculiarities of Chemical Binding in Anhydrous Lead(II) and Tin(II) Hexacyanoferrates(II,III)

被引：0
|
作者：
V. M. Zainullina
V. P. Zhukov
V. G. Zubkov
A. P. Tyutyunnik
L. G. Maksimova
T. A. Denisova
机构：
[1] Russian Academy of Sciences,Institute of Solid State Chemistry, Ural Branch
来源：
Journal of Structural Chemistry | 2004年 / 45卷
关键词：
electronic structure; calculations; chemical binding; hexacyanoferrates;
D O I：
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中图分类号：
学科分类号：
摘要：
The electronic structure and chemical binding of anhydrous lead and tin hexacyanoferrates(II,III) Pb2Fe(CN)6, Pb1.5Fe(CN)6, and Sn2Fe(CN)6 were studied by the linear muffm-tin orbital (tight binding approximation) and extended Hückel theory methods. The general tendencies of variation for the stability of the Pb–N, Sn–N, Fe–C, and C–N bonds were determined for Pb2Fe(CN)6, Pb1.5Fe(CN)6, and Sn2Fe(CN)6 crystals. Peculiarities of Pb(Sn)–N chemical interactions in the structure of the phases have been found.
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页码：201 / 205
页数：4
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