New tetrathiafulvalenes containing a 2,5-bis(thiophen-2-yl)pyrrole fragment: Synthesis, optical properties, and electrochemical behavior

被引：0
|
作者：
E. A. Ignatenko
E. V. Shklyaeva
G. G. Abashev
机构：
[1] Russian Academy of Sciences,Institute of Technical Chemistry, Ural Branch
[2] Perm State National Research University,Institute of Natural Sciences
来源：
Russian Journal of Organic Chemistry | 2013年 / 49卷
关键词：
Pyrrole; Thiophene; Tetrathiafulvalenes; Methylsulfanyl; Triethyl Phosphite;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The reaction of 1-(3-bromopropyl)-2,5-bis(thiophen-2-yl)-1H-pyrrole with cesium 5-methylsulfanyl-2-thioxo-1,3-dithiole-4-thiolate generated in situ gave previously unknown 4-{3-[2,5-bis(thiophen-2-yl)-1H-pyrrol-1-yl]propylsulfanyl}-5-methylsulfanyl-1,3-dithiole-2-thione, and cross-coupling of the latter with 4,5-disubstituted 1,3-dithiole-2-thiones in the presence of triethyl phosphite afforded new substituted tetrathiafulvalenes containing a 2,5-bis(thiophen-2-yl)pyrrole fragment. Optical properties and electrochemical behavior of the synthesized compounds were studied, and their ability to undergo electropolymerization was confirmed.
引用
收藏
页码：1379 / 1385
页数：6
相关论文
共 50 条
  • [31] New strategy for the synthesis of 3-ethynyl-2-(thiophen-2-yl)benzo[b]thiophene derivatives
    Muheb A. S. Algso
    Arif Kivrak
    Chemical Papers, 2019, 73 : 977 - 985
  • [32] A new synthesis of 2,5-bis(4-cyanophenyl)furan
    Suthiwangcharoen, Nisaraporn
    Stephens, Chad E.
    ARKIVOC, 2006, : 122 - 127
  • [33] 2,5-BIS(PIPERIDINOMETHYL)PYRROLE AND (2,5-PYRROLEDIYLDIMETHYLENE)BIS(TRIPHENYLPHOSPHONIUM IODIDE) - SYNTHESIS AND REACTIONS LEADING TO [2.2](2,5)PYRROLOPHANES AND 2,5-BISVINYL-SUBSTITUTED PYRROLES
    FLITSCH, W
    KNEIP, HG
    LIEBIGS ANNALEN DER CHEMIE, 1985, (09): : 1895 - 1903
  • [34] Donor-acceptor alternating π-conjugated polymers containing Di(thiophen-2-yl)pyrene and 2,5-Bis(2-octyldodecyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione for organic thin-film transistors
    Yang, Da Seul
    Kim, Kyung Hwan
    Cho, Min Ju
    Jin, Jung-Il
    Choi, Dong Hoon
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2013, 51 (06) : 1457 - 1467
  • [35] Photoreactivity, Optical Behavior and DFT Studies of 2,5-Bis[4-choloro-acetyl(thiophen-2-ylmethylene)]cyclopentanone BCTCP in Different Solvents
    Hussein, M. A.
    Osman, O. I.
    Asiri, A. M.
    Rozman, H. D.
    El-Daly, S. A.
    JOURNAL OF FLUORESCENCE, 2017, 27 (03) : 1129 - 1140
  • [36] Photoreactivity, Optical Behavior and DFT Studies of 2,5-Bis[4-choloro-acetyl(thiophen-2-ylmethylene)]cyclopentanone BCTCP in Different Solvents
    M. A. Hussein
    O. I. Osman
    A. M. Asiri
    H. D. Rozman
    S. A. El-Daly
    Journal of Fluorescence, 2017, 27 : 1129 - 1140
  • [37] Synthesis and Characterization of Red-Emitting Poly(aryleneethynylene)s Based on 2,5-Bis(2-ethylhexyl)-3,6-di(thiophen-2-yl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione (DPP)
    Palai, Akshaya K.
    Mishra, Sarada P.
    Kumar, Amit
    Srivastava, Ritu
    Kamalasanan, Modeeparampil N.
    Patri, Manoranjan
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2010, 211 (09) : 1043 - 1053
  • [38] Synthesis, structural characterization and catalysis of ruthenium(II) complexes based on 2,5-bis(2′-pyridyl) pyrrole ligand
    Zhong, Yi-Qing
    Xiao, Hui-Qiong
    Yi, Xiao-Yi
    DALTON TRANSACTIONS, 2016, 45 (45) : 18113 - 18119
  • [39] ortho-Substituted (Aryl)(3-nitrobenzo[b]thiophen-2-yl)amines: Study of the Electrochemical Behavior
    Cosimelli, Barbara
    Lanza, Camilla Zaira
    Scavetta, Erika
    Severi, Elda
    Spinelli, Domenico
    Stenta, Marco
    Tonelli, Domenica
    JOURNAL OF PHYSICAL CHEMISTRY A, 2009, 113 (38): : 10260 - 10263
  • [40] Design, Synthesis and Photovoltaic Performance of Novel Conjugated Polymers Based on Difluorobenzothiadiazole and 2,3-Bis[thiophen-2-yl]acrylonitrile
    Zheng Jiang-Bo
    Chen Zhi-Ming
    Hu Zhi-Cheng
    Zhang Jie
    Huang Fei
    ACTA PHYSICO-CHIMICA SINICA, 2017, 33 (08) : 1635 - 1643
12345