New tetrathiafulvalenes containing a 2,5-bis(thiophen-2-yl)pyrrole fragment: Synthesis, optical properties, and electrochemical behavior

被引：0
|
作者：
E. A. Ignatenko
E. V. Shklyaeva
G. G. Abashev
机构：
[1] Russian Academy of Sciences,Institute of Technical Chemistry, Ural Branch
[2] Perm State National Research University,Institute of Natural Sciences
来源：
Russian Journal of Organic Chemistry | 2013年 / 49卷
关键词：
Pyrrole; Thiophene; Tetrathiafulvalenes; Methylsulfanyl; Triethyl Phosphite;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The reaction of 1-(3-bromopropyl)-2,5-bis(thiophen-2-yl)-1H-pyrrole with cesium 5-methylsulfanyl-2-thioxo-1,3-dithiole-4-thiolate generated in situ gave previously unknown 4-{3-[2,5-bis(thiophen-2-yl)-1H-pyrrol-1-yl]propylsulfanyl}-5-methylsulfanyl-1,3-dithiole-2-thione, and cross-coupling of the latter with 4,5-disubstituted 1,3-dithiole-2-thiones in the presence of triethyl phosphite afforded new substituted tetrathiafulvalenes containing a 2,5-bis(thiophen-2-yl)pyrrole fragment. Optical properties and electrochemical behavior of the synthesized compounds were studied, and their ability to undergo electropolymerization was confirmed.
引用
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页码：1379 / 1385
页数：6
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