Spectroscopic and structural properties of 2,2′-dipyridylamine and its palladium and platinum complexes

被引：0
|
作者：
Ş. Yurdakul
M. T. Bilkana
机构：
[1] Gazi University,Department of Physics, Faculty of Science
[2] Karatekin University,Department of Physics, Faculty of Science
来源：
Optics and Spectroscopy | 2015年 / 119卷
关键词：
Bond Length; Palladium; Density Functional Theory; Free Ligand; Platinum Complex;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The structural features such as geometric parameters, vibration frequencies and intensities of the vibrational bands of 2,2′-dipyridylamine ligand (DPA), its palladium (Pd(DPA)Cl2) and platinum (Pt(DPA)Cl2) complexes were studied by the density functional theory (DFT). The calculations were carried out by DFT / B3LYP method with 6-311++G(d,p) and LANL2DZ basis sets. All vibrational frequencies assigned in detail with the help of total energy distribution analysis (TED). Optimized geometric bond lengths and bond angles were compared with experimental X-ray data. Using DPA, K2PtCl4, and Na2PdCl4, the synthesized complex structures were characterized by the combination of elemental analysis, FT-IR (mid and far IR) and Raman spectroscopy.
引用
收藏
页码：603 / 619
页数：16
相关论文
共 50 条
  • [21] Thermoanalytical, magnetic and structural investigation of neutral Co(II) complexes with 2,2′-dipyridylamine and salicylaldehydes
    Christos Papadopoulos
    Beata Cristóvão
    Wieslawa Ferenc
    Antonios Hatzidimitriou
    Stefano Vecchio Ciprioti
    Roberta Risoluti
    Maria Lalia-Kantouri
    Journal of Thermal Analysis and Calorimetry, 2016, 123 : 717 - 729
  • [22] Crystal structure, DNA-binding ability and cytotoxic activity of platinum(II) 2,2′-dipyridylamine complexes
    Tu, C
    Wu, XF
    Liu, Q
    Wang, XY
    Xu, Q
    Guo, ZJ
    INORGANICA CHIMICA ACTA, 2004, 357 (01) : 95 - 102
  • [23] STRUCTURAL-PROPERTIES OF R2PCH2PR2-BRIDGED COMPLEXES OF PALLADIUM AND PLATINUM
    MANOJLOVICMUIR, L
    MUIR, KW
    ACTA CRYSTALLOGRAPHICA SECTION A, 1984, 40 : C292 - C292
  • [24] Crystal structure of cis-dichloro (2,2′-dipyridylamine)-platinum(II)
    Li, DC
    Liu, DJ
    CRYSTAL RESEARCH AND TECHNOLOGY, 2004, 39 (04) : 359 - 362
  • [25] FAR INFRARED SPECTRA OF PALLADIUM COMPOUNDS .2. PYRIDINE AND 2,2'-BIPYRIDYL COMPLEXES OF PALLADIUM (2) AND PLATINUM(2)
    DURIG, JR
    MITCHELL, BR
    SINK, DW
    WILLIS, JN
    WILSON, AS
    SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY, 1967, A 23 (04): : 1121 - &
  • [26] PREPARATION AND PROPERTIES OF NICKEL(2) AND PALLADIUM(2) COMPLEXES OF 2,2'-BIPHENYLYLENEBISDIETHYLPHOSPHINE . SPECTROSCOPIC MAGNETIC AND PROTON MAGNETIC RESONANCE STUDIES
    ALLEN, DW
    MILLAR, IT
    MANN, FG
    CANADINE, RM
    WALKER, J
    JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1969, (07): : 1097 - &
  • [27] Deciphering Spectroscopic and Structural Insights into the Photophysical Behavior of 2,2′-Dipyridylamine: An Efficient Environment Sensitive Fluorescence Probe
    Rohman, Mostofa Ataur
    Phanrang, Pynskhemborlang T.
    Chamlagai, Dipak
    Mitra, Sivaprasad
    JOURNAL OF PHYSICAL CHEMISTRY A, 2021, 125 (32): : 6964 - 6975
  • [28] Luminescent mononuclear and binuclear cyclometalated palladium(II) complexes of 6-phenyl-2,2′-bipyridines:: Spectroscopic and structural comparisons with platinum(II) analogues
    Lai, SW
    Cheung, TC
    Chan, MCW
    Cheung, KK
    Peng, SM
    Che, CM
    INORGANIC CHEMISTRY, 2000, 39 (02) : 255 - 262
  • [29] Spectroscopic and electrochemical studies of some molybdenum and ruthenium complexes of N-[(2-pyridyl)methyl]-2,2′-dipyridylamine
    Ramadan, RM
    Hamza, MSA
    Mohamed, HA
    El-Medani, SM
    TRANSITION METAL CHEMISTRY, 2006, 31 (01) : 107 - 110
  • [30] Spectroscopic and Electrochemical Studies of Some Molybdenum and Ruthenium Complexes of N-[(2-pyridyl)methyl]-2,2′-dipyridylamine
    Ramadan M. Ramadan
    Mohamed S. A. Hamza
    Hassan A. Mohamed
    Samir M. El-Medani
    Transition Metal Chemistry, 2006, 31 : 107 - 110
12345