New Synthetic Routes to More Active Cu/ZnO Catalysts Used for Methanol Synthesis

被引:0
|
作者
Melanie Kurtz
Natalia Bauer
Christoph Büscher
Hagen Wilmer
Olaf Hinrichsen
Ralf Becker
Stefan Rabe
Klaus Merz
Matthias Driess
Roland A. Fischer
Martin Muhler
机构
[1] Ruhr-University Bochum,Laboratory of Industrial Chemistry
[2] Pilkington Deutschland AG,Inorganic Chemistry II: Organometallics and Materials Chemistry
[3] Ruhr-University Bochum,Inorganic Chemistry I: Cluster and Coordination Chemistry
[4] Ruhr-University Bochum,undefined
来源
Catalysis Letters | 2004年 / 92卷
关键词
Cu-based catalysts; methanol synthesis; coprecipitation; deposition–precipitation; chemical vapor deposition (CVD); area-activity relationship; Cu-ZnO interface;
D O I
暂无
中图分类号
学科分类号
摘要
New preparation routes are applied to synthesize novel Cu/ZnO catalysts exhibiting high catalytic activity in methanol synthesis. In particular, the deposition–precipitation of copper onto high specific surface area (SSA) zinc oxide particles and the chemical vapor deposition of diethyl zinc turned out to be effective techniques, leading to promising methanol synthesis catalysts due to the enlargement of the Cu-ZnO interface.
引用
收藏
页码:49 / 52
页数:3
相关论文
共 50 条
  • [41] Comment on "Active sites for CO2 hydrogenation to methanol on Cu/ZnO catalysts"
    Nakamura, Junji
    Fujitani, Tadahiro
    Kuld, Sebastian
    Helveg, Stig
    Chorkendorff, Ib
    Sehested, Jens
    SCIENCE, 2017, 357 (6354)
  • [42] CU/ZNO(0001-BAR) AND ZNOX/CU(111) - MODEL CATALYSTS FOR METHANOL SYNTHESIS
    CAMPBELL, CT
    DAUBE, KA
    WHITE, JM
    SURFACE SCIENCE, 1987, 182 (03) : 458 - 476
  • [43] Active sites in Cu/ZnO/ZrO2 catalysts for methanol synthesis from CO/H2
    Suh, YW
    Moon, SH
    Rhee, HK
    CATALYSIS TODAY, 2000, 63 (2-4) : 447 - 452
  • [44] The difference in the active sites for CO2 and CO hydrogenations on Cu/ZnO-based methanol synthesis catalysts
    Y. Choi
    K. Futagami
    T. Fujitani
    J. Nakamura
    Catalysis Letters, 2001, 73 : 27 - 31
  • [45] The difference in the active sites for CO2 and CO hydrogenations on Cu/ZnO-based methanol synthesis catalysts
    Choi, Y
    Futagami, K
    Fujitani, T
    Nakamura, J
    CATALYSIS LETTERS, 2001, 73 (01) : 27 - 31
  • [46] Identifying the nature of the active sites in methanol synthesis over Cu/ZnO/Al2O3 catalysts
    Laudenschleger, Daniel
    Ruland, Holger
    Muhler, Martin
    NATURE COMMUNICATIONS, 2020, 11 (01)
  • [47] Identifying the nature of the active sites in methanol synthesis over Cu/ZnO/Al2O3 catalysts
    Daniel Laudenschleger
    Holger Ruland
    Martin Muhler
    Nature Communications, 11
  • [48] New preparation method of Cu/ZnO catalysts for methanol synthesis from carbon dioxide hydrogenation by mechanical alloying
    Fukui, H
    Kobayashi, M
    Yamaguchi, T
    Kusama, H
    Sayama, K
    Okabe, K
    Arakawa, H
    ADVANCES IN CHEMICAL CONVERSIONS FOR MITIGATING CARBON DIOXIDE, 1998, 114 : 529 - 532
  • [49] SYNERGY BETWEEN CU AND ZNO FOR METHANOL CONVERSIONS OVER CU-ZNO CATALYSTS
    OKAMOTO, Y
    FUKINO, K
    IMANAKA, T
    TERANISHI, S
    CHEMISTRY LETTERS, 1984, (01) : 71 - 74
  • [50] The active site for methanol synthesis on a Cu/ZnO/SiO2 catalyst
    Rochester, CH
    CATALYSIS LETTERS, 1998, 52 (1-2) : 121 - 121