Crystallization from high-temperature solutions in the Na2O-Bi2O3-P2O5-MVIO3 (M = Mo, W) systems

被引：0
|
作者：
K. V. Terebilenko
I. V. Zatovsky
N. S. Slobodyanik
V. N. Baumer
V. G. Zatovsky
机构：
[1] Shevchenko National University,Institute of Single Crystals
[2] National Academy of Sciences of Ukraine,Frantsevich Institute of Materials Science Problems
[3] National Academy of Sciences of Ukraine,undefined
来源：
Inorganic Materials | 2007年 / 43卷
关键词：
Bismuth; Bismuth Oxide; Bismuth Molybdate; Double Orthophosphate; Sodium Metaphosphate;
D O I：
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学科分类号：
摘要：
We have studied the crystallization behavior of Na2O-NaPO3-MVIO3(MVI = Mo, W) high-temperature solutions containing 15 mol % Bi2O3 in the pseudoquaternary systems Na2O-Bi2O3-P2O5-MVIO3 and have established the conditions for the formation of Na3Bi(PO4)2, high-temperature BiPO4, NaBi(MoO4)2, Bi2WO6, and NaMoO2PO4. The compounds identified have been characterized by powder x-ray diffraction and IR spectroscopy.
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页码：1336 / 1339
页数：3
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