Effect of electron-electron correlations on the activation free energy of adiabatic electrochemical reactions of dissociative electron transfer

被引：0

作者：

A. M. Kuznetsov

I. G. Medvedev

V. V. Sokolov

机构：

[1] Russian Academy of Sciences,Frumkin Institute of Electrochemistry

来源：

Russian Journal of Electrochemistry | 2005年 / 41卷

关键词：

dissociative electron transfer; Anderson model; effects of electron-electron correlations; adiabatic free energy surface;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Adiabatic free energy surfaces for adiabatic electrochemical reactions of dissociative electron transfer are calculated with exact allowance for the effects of electron-electron correlations in a model of an electrode with an infinitely broad conduction band. The role of correlation effects in these reactions is discussed. It is shown that, as in common adiabatic electrochemical reactions of electron transfer, correlation effects play a substantial role and lead to a considerable decrease in the activation free energies.

引用

页码：361 / 367

页数：6

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