A Selective Conversion of Benzylic Alcohols to the Corresponding Carbonyl Compounds by Means of an Ag(III) Complex

被引：0

作者：

Zorica Bugarcěić

Slobodan Novokmet

Zěeljko Senić

Zěivadin Bugarcěić

机构：

[1] University of Kragujevac,

[2] Faculty of Science,undefined

[3] Department of Chemistry,undefined

[4] YU-34000 Kragujevac,undefined

[5] Yugoslavia,undefined

来源：

Monatshefte für Chemie / Chemical Monthly | 2000年 / 131卷

关键词：

Keywords. Alcohols; Aldehydes; Diperiodato-argentate(III) complex; Ketones; Oxidations.;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Carbonyl compounds of the type XPhCOR (R = H, Me, Ph; X = H, Me, Cl, Br) are prepared in high yields by reaction of the corresponding benzylic alcohols XPhCHOHR with KNa4 [Ag(HIO6)2]×12H2O in alkaline solution. This method allows the selective oxidation of benzylic alcohols in compounds containing other types of alcoholic functional groups.

引用

页码：799 / 802

页数：3

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