Selective oxidation of some primary and secondary benzylic alcohols to the corresponding carbonyl compounds with a Cu(III) complex

被引：2
|
作者：
Bugarcic, Z [1 ]
Novokmet, S
Kostic, V
机构：
[1] Univ Kragujevac, Fac Sci, Dept Chem, Kragujevac 34000, Serbia Monteneg
[2] Univ Erlangen Nurnberg, Inst Inorgan Chem, D-91058 Erlangen, Germany
来源：
JOURNAL OF THE SERBIAN CHEMICAL SOCIETY | 2005年 / 70卷 / 05期
关键词：
alcohols; aldehydes; ketones; oxidations;
D O I：
10.2298/JSC0505681B
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The selective oxidation of benzylic alcohols to the corresponding carbonyl compounds is described. In alkaline solution, the oxidation reagent potassium tetrasodium diperiodatocuprate(III) dodecahydrate (KNa4[Cu(HIO6)(2)]x12H(2)O) reacts with primary and secondary benzylic alcohols whereby good yields of the corresponding carbonyl compounds are obtained. The presented method provides for the selective oxidation of the benzylic hydroxyl group in compounds containing other types of alcoholic functional groups.
引用
收藏
页码：681 / 686
页数：6
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