Reaction of Free Methyl Cation with (Isobutylamino)trimethylsilane in the Gas Phase. A Radiochemical and Quantum-Chemical Study

被引：0
|
作者：
T. A. Kochina
D. V. Vrazhnov
E. N. Sinotova
M. Yu. Katsap
B. F. Shchegolev
机构：
[1] Russian Academy of Sciences,Institute of Silicate Chemistry
[2] St. Petersburg State University,undefined
来源：
Russian Journal of General Chemistry | 2001年 / 71卷
关键词：
Methyl; Bond Cleavage; Proton Transfer; Reaction Channel; Major Reaction;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The reaction of free methyl cation with (isobutylamino)trimethylsilane was studied by the radiochemical method. Like with organic amines and silazane, the reaction occurs by two channels: condensation and proton transfer. Proton transfer remains to be the major reaction channel, while its contribution is less that with amines and silazane. The radiochemical and quantum-chemical methods were used to show that the condensation and proton-transfer complexes decompose primarily via Si-N bond cleavage.
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页码：1557 / 1561
页数：4
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