New ruthenocene-based ruthenium pincer complex bearing the C5Me4CF3 ligand

被引：0
|
作者：
S. V. Safronov
A. A. Koridze
机构：
[1] Russian Academy of Sciences,A. N. Nesmeyanov Institute of Organoelement Compounds
[2] I. Javakhishvili Tbilisi State University,Institute of Organometallic Chemistry
来源：
Russian Chemical Bulletin | 2018年 / 67卷
关键词：
ruthenium; (trifluoromethyl)tetramethylruthenocene; ruthenocene; metallocene; diol; bisphosphine ligand; pincer complex;
D O I：
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学科分类号：
摘要：
The first (trifluoromethyl)tetramethylruthenocene-based ruthenium pincer complex RuCl(CO)[{2,5-(Bu2tPCH2)2C5H2}Ru(C5Me4CF3)] was synthesized by cyclometallation of the bisphosphine ligand {1,3-(Bu2tPCH2)2C5H2}Ru(C5Me4CF3) with RuCl2(DMSO)4 in 2-methoxyethanol in the presence of NEt3. The new complex was fully characterized by 1H, 19F, 31P{1H}, 13C{1H} NMR and IR spectroscopy.
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页码：1247 / 1250
页数：3
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