New ruthenocene-based ruthenium pincer complex bearing the C5Me4CF3 ligand

被引：0

作者：

S. V. Safronov

A. A. Koridze

机构：

[1] Russian Academy of Sciences,A. N. Nesmeyanov Institute of Organoelement Compounds

[2] I. Javakhishvili Tbilisi State University,Institute of Organometallic Chemistry

来源：

Russian Chemical Bulletin | 2018年 / 67卷

关键词：

ruthenium; (trifluoromethyl)tetramethylruthenocene; ruthenocene; metallocene; diol; bisphosphine ligand; pincer complex;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The first (trifluoromethyl)tetramethylruthenocene-based ruthenium pincer complex RuCl(CO)[{2,5-(Bu2tPCH2)2C5H2}Ru(C5Me4CF3)] was synthesized by cyclometallation of the bisphosphine ligand {1,3-(Bu2tPCH2)2C5H2}Ru(C5Me4CF3) with RuCl2(DMSO)4 in 2-methoxyethanol in the presence of NEt3. The new complex was fully characterized by 1H, 19F, 31P{1H}, 13C{1H} NMR and IR spectroscopy.

引用

页码：1247 / 1250

页数：3

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