Crystallographic Analysis of Compounds with Lindqvist Polyanions: Coherent Assembly, Symmetry, Stability

被引：0
|
作者：
S. V. Borisov
S. A. Magarill
N. V. Pervukhina
机构：
[1] Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry, Siberian Branch
来源：
Journal of Structural Chemistry | 2018年 / 59卷
关键词：
Lindqvist polyanion; crystallographic analysis; cation sublattices; coherent assembly; relative stability of crystal structures;
D O I：
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中图分类号：
学科分类号：
摘要：
The crystallographic analysis of the structure of three inorganic compounds with Lindqvist polyanions establishes that their structural arrangement is determined by the geometry and symmetry of the [M6] cation octahedron by the coherent assembly of [M6O19] building blocks. The relative stability of the structures is estimated from the number of degrees of freedom of their atoms and the fundamental volumes characterizing the degree of symmetrization of the structures.
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页码：612 / 617
页数：5
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