Synthesis and Reactivity of Porphyrin Complexes of Group IV p-Elements

被引:0
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作者
O. V. Molodkina
T. N. Lomova
E. G. Mozhzhukhina
机构
[1] Russian Academy of Sciences,Institute of Solution Chemistry
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关键词
Porphyrin; Complex Formation; Steric Factor; General Regularity; Porphyrin Complex;
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摘要
The composition of products and the general regularities of complex formation of meso-tetraphenylporphine with Si(IV), Ge(IV), Sn(II), and Pb(II), as well as the kinetics and mechanism of dissociation of the resulting complexes under the action of proton-donor reagents were studied. The nature of chemical and steric factors that operate to stabilize mixed-ligand acido porphyrin p-metal complexes was revealed.
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页码:968 / 973
页数:5
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