Synthesis and Reactivity of Porphyrin Complexes of Group IV p-Elements

被引：0
|
作者：
O. V. Molodkina
T. N. Lomova
E. G. Mozhzhukhina
机构：
[1] Russian Academy of Sciences,Institute of Solution Chemistry
来源：
Russian Journal of General Chemistry | 2002年 / 72卷
关键词：
Porphyrin; Complex Formation; Steric Factor; General Regularity; Porphyrin Complex;
D O I：
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中图分类号：
学科分类号：
摘要：
The composition of products and the general regularities of complex formation of meso-tetraphenylporphine with Si(IV), Ge(IV), Sn(II), and Pb(II), as well as the kinetics and mechanism of dissociation of the resulting complexes under the action of proton-donor reagents were studied. The nature of chemical and steric factors that operate to stabilize mixed-ligand acido porphyrin p-metal complexes was revealed.
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页码：968 / 973
页数：5
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