Evolution of Fe3+-hydrogel for catalytic reduction of 4-nitrophenol

被引:0
|
作者
Yian Zheng
Yongfeng Zhu
Aiqin Wang
机构
[1] Chinese Academy of Sciences,Center of Eco
[2] Key Laboratory for Environment Pollution Prediction and Control (Gansu Province),materials and Green Chemistry, Lanzhou Institute of Chemical Physics
[3] College of Earth and Environment Sciences,undefined
[4] Lanzhou University,undefined
[5] University of Chinese Academy of Sciences,undefined
来源
关键词
Granular hydrogel; Size-confined reactor; Ion crosslinking; Catalytic reduction; 4-Nitrophenol;
D O I
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中图分类号
学科分类号
摘要
A granular hydrogel was prepared under ambient conditions using chitosan as the graft backbone, acrylic acid as the monomer, and ascorbic acid/hydrogen peroxide (Vc/H2O2) as the redox initiator, and then crosslinked with Fe3+ ions. The resulting Fe3+-hydrogel was tested for the catalytic reduction of 4-nitrophenol (4-NP), with the finding that in the presence of NaBH4 and an inert atmosphere, 5 mg/L 4-NP can be completely reduced by Fe3+-hydrogel within 30 min. Also, Fe3+-hydrogel exhibits an excellent reusability for ten successive catalytic cycles.
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页码:2009 / 2016
页数:7
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