Synthesis of a new cubic phase in the B-C-N system

被引：0
|
作者：
V. P. Filonenko
V. N. Khabashesku
V. A. Davydov
I. P. Zibrov
V. N. Agafonov
机构：
[1] Russian Academy of Sciences,Vereshchagin Institute of High
[2] Rice University,Pressure Physics
[3] Russian Academy of Sciences,Department of Chemistry, Rice Quantum Institute and Center for Nanoscale Science and Technology
[4] Université François-Rabelais Tours,Shubnikov Institute of Crystallography
来源：
Inorganic Materials | 2008年 / 44卷
关键词：
Boron; Nitride; Boron Nitride; Interlayer Spacing; Boron Atom;
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摘要：
Phase formation in the B-C-N system has been studied at pressures from 6 to 15 GPa and temperatures from 1000 to 1600°C using mixtures of carbon nitride (C3N4) nanospheres and boron. A new ternary phase with the structure of cubic boron nitride in which some of the nitrogen and boron atoms are replaced by carbon has been obtained at p ≃ 8 GPa and t ≃ 1500°C. According to the Rietveld refinement results, its composition is BC0.47N0.85.
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