Study on the thermal decomposition kinetics ofcis/trans-[Cu(gly)2] • H2O

被引：0
|
作者：
Fengxing Zhang
Jun Li
Hengxin Li
Guixiang Du
Shuqing Song
机构：
[1] Northwest University/Shaanxi Province Key Laboratory of Physicoinorganic Chemistry,Chemistry Department
来源：
Science in China Series B: Chemistry | 2005年 / 48卷
关键词：
copper(II) complex; thermal analysis; thermal decomposition kinetics; cis/trans isomers; glycin;
D O I：
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学科分类号：
摘要：
The thermal decomposition reactions of the complexescis/trans-[Cu(gly)2] • H2O were studied by TG-DSC methods. The results showed that they have similar decomposition process, which occur in two steps. The first step is the loss of water and the second step is the decomposition of anhydrous complexes. But forcis-[Cu(gly)2]•H2O, the temperature of losing water is higher than that oftrans-isomer. Their reaction mechanisms of the two-step decomposition were also proposed.
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页码：70 / 73
页数：3
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