Copolymerization of vinyl chloride with 1-vinyl-4,5,6,7-tetrahydroindole and 2-methyl-5-vinylpyridine

被引：0
|
作者：
N. S. Shaglaeva
O. V. Lebedeva
Yu. N. Pozhidaev
R. G. Sultangareev
M. V. Markova
V. N. Salaurov
机构：
[1] Russian Academy of Sciences,Favorskii Institute of Chemistry, Siberian Branch
[2] Irkutsk State Technical University,undefined
来源：
Polymer Science Series B | 2008年 / 50卷
关键词：
Copolymerization; Polymer Science Series; AIBN; Vinyl Chloride; Hydrogen Chloride;
D O I：
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学科分类号：
摘要：
The radical copolymerization of vinyl chloride with 2-methyl-5-vinylpyridine and 1-vinyl-4,5,6,7-tetrahydroindole is accompanied by dehydrochlorination. In the vinyl chloride-2-methyl-5-vinylpyridine system, the evolved hydrogen chloride interacts with a pyridine hydrogen atom to give charged units of a heterocycle. In the vinyl chloride-1-vinyl-4,5,6,7-tetrahydroindole system, the hydrogen chloride being formed initiates the cationic dimerization of a nitrogen-containing monomer. The synthesized copolymers based on vinyl chloride surpass the commercial poly(vinyl chloride) in terms of thermal stability and solubility in organic solvents.
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页码：315 / 320
页数：5
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