Organophosphines in organoplatinum complexes: structural aspects of PtPCX2 (X = OL, NL, Cl, SL, SeL, SiL, Br or I) derivatives

被引：0

作者：

Milan Melník

Peter Mikuš

机构：

[1] Comenius University in Bratislava,Department of Pharmaceutical Analysis and Nuclear Pharmacy, Faculty of Pharmacy

[2] Comenius University in Bratislava,Toxicological and Antidoping Center, Faculty of Pharmacy

来源：

Transition Metal Chemistry | 2017年 / 42卷

关键词：

D O I：

暂无

中图分类号：

学科分类号：

摘要：

In this review are classified and analyzed the structural parameters of eighty monomeric organoplatinum complexes with inner coordination spheres of PtPCX2 (X = OL, NL, Cl, SL, SeL, SiL, Br or I). These complexes crystallized in four crystal systems: cubic, orthorhombic, monoclinic and triclinic. Distorted square planar environments about the Pt(II) atoms are built up from monodentate, homobidentate, heterobidentate and heterotridentate donor ligands. The chelating ligands create wide varieties of metallocycles. These are discussed in terms of the coordination about the platinum atom, and correlations are drawn between donor atoms, bond lengths and interbond angles, with particular attention to any trans-influence. There are complexes with cis- as well as trans-configurations, but the former by far prevail. The Pt–L bonds in the complexes with cis-configuration appear to be more polar and presumably weaker than those in their trans-partners.

引用

页码：673 / 682

页数：9

共 50 条

[21] Characterization of orthogonal hydrogen and halogen bonds in thiobarbituric acid complexes with halogen molecules (X = I2, Br2, and Cl2): Structural and spectroscopic study
Alosaimi, Abeer M.
Aljehani, Abdulrahman S.
Ibrahim, Mohamed M.
El-Sheshtawy, Hamdy S.
Altalhi, Tariq
JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2021, 68 (09) : 1630 - 1636
[22] Structural and Spectroscopic Evidence for Marginal Metal-to-Ligand Charge Transfer in Complexes Pt(abpy)Me3X, abpy=2,2′-Azobispyridine, X = Cl, Br, I
Dogan, Akbey
Kavakli, Cueneyt
Sieger, Monika
Niemeyer, Mark
Sarkar, Biprajit
Kaim, Wolfgang
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2008, 634 (14): : 2527 - 2531
[23] Revealing the structural, electronic and optical properties of lead-free perovskite derivatives of Rb2SnX6(X = Cl, Br and I): A theory calculation
Tang, Yong
Zhang, Jihua
Zhong, Xiangli
Wang, Qianjin
Zhang, Heng
Ren, Chuanlai
Wang, Jinbin
SOLAR ENERGY, 2019, 190 : 272 - 277
[24] Complexes of BX3 with EMe2 (X = F, Cl, Br, I; E - Se or Te): Synthesis, multinuclear NMR spectroscopic and structural studies
Okio, Coco K. Y. A.
Levason, William
Monzittu, Francesco M.
Reid, Gillian
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2017, 848 : 232 - 238
[25] Structural and dynamic properties of OsH2X2L2 (X = Cl, Br, I; L = PiPt3) complexes. Interconversion between remarkable non-octahedral isomers
1600, ACS, Washington, DC, USA (117):
[26] Structural comparison of [PdX2(P-P)] complexes (X- = Cl, Br and I; P-P = α,ω-bis(diphenylphosphino)alkanes) and their trends of redox potentials
Abukari, Moses Abdullai
Suzuki, Takayoshi
Kita, Masakazu
POLYHEDRON, 2013, 52 : 364 - 369
[27] First-principles calculations to investigate structural, elastic, electronic and optical properties of lead-free perovskite derivatives Cs2SeX6 (X=Cl, Br, I)
Hu, De-Yuan
Zhao, Xian-Hao
Tang, Tian-Yu
Li, Li
Gao, Li-Ke
Tang, Yan-Lin
OPTICAL MATERIALS, 2021, 119
[28] Investigation into relative stability of structural and electron characteristics of gold complexes [AuX2]- (X = SCN, CN, F, Cl, Br, I) and [Au(SC(NH2)2)2]+ by methods of quantum chemistry
Randin, O. I.
RUSSIAN JOURNAL OF NON-FERROUS METALS, 2012, 53 (01) : 35 - 37
[29] Investigation into relative stability of structural and electron characteristics of gold complexes [AuX2]− (X = SCN, CN, F, Cl, Br, I) and [Au(SC(NH2)2)2]+ by methods of quantum chemistry
O. I. Randin
Russian Journal of Non-Ferrous Metals, 2012, 53 : 35 - 37
[30] Copper(I) coordination polymers[{Cu(μ-X)}2{RP(μ-NtBu)}2]n (R = OC6H4OMe-o;: X = Cl, Br, and I) and their reversible conversion into mononuclear complexes [CuX{(RP(μ-NtBu))2}2]:: Synthesis and structural characterization
Chandrasekaran, P.
Mague, Joel T.
Balakrishna, Maravanji S.
INORGANIC CHEMISTRY, 2006, 45 (17) : 6678 - 6683

← 1 2 3 4 5 →