X-ray absorption spectroscopy (NEXAFS) of polymer surfaces

被引：0
|
作者：
W. E. S. Unger
A. Lippitz
C. Wöll
W. Heckmann
机构：
[1] Bundesanstalt für Materialforschung und -prüfung (BAM),
[2] Labor VIII.23,undefined
[3] D-12200 Berlin,undefined
[4] Germany,undefined
[5] Angewandte Physikalische Chemie am Physikalisch-Chemischen Institut der Universität Heidelberg,undefined
[6] D-69120 Heidelberg,undefined
[7] Germany,undefined
[8] BASF AG,undefined
[9] Kunststofflaboratorium,undefined
[10] D-67056 Ludwigshafen,undefined
[11] Germany,undefined
来源：
Fresenius' Journal of Analytical Chemistry | 1997年 / 358卷
关键词：
Styrene; Preferential Orientation; Plasma Treatment; Surface Analysis; Terephthalate;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The application of X-ray absorption spectroscopy (NEXAFS) in surface analysis of polymers is demonstrated by means of selected examples. High resolution NEXAFS spectra of poly(ethylene), poly(butadiene) and poly(styrene) are presented. The effect of oxygen plasma treatment on the surface of polypropylene foils was investigated. It is shown that angle resolved NEXAFS spectroscopy can be used to observe preferential orientations of segments of macromolecules at the surface of a poly(ethylene terephthalate) foil. Finally, the formation of a polymer-metal interface was observed in a model study of chromium evaporated onto a poly(bisphenol-A-carbonate) film surface. NEXAFS spectroscopy and XPS are complementary tools in surface analysis of polymers. NEXAFS polymer spectra can be used in parallel electron energy loss spectroscopy (PEELS) to control for electron beam damage.
引用
收藏
页码：89 / 92
页数：3
相关论文
共 50 条
  • [31] X-RAY SPECTROSCOPY OF POLYMER ELECTROLYTES
    AZIZ, M
    LATHAM, RJ
    LINFORD, RG
    SCHLINDWEIN, WS
    ELECTROCHIMICA ACTA, 1995, 40 (13-14) : 2119 - 2122
  • [32] High resolution X-ray emission and X-ray absorption spectroscopy
    de Groot, F
    CHEMICAL REVIEWS, 2001, 101 (06) : 1779 - 1808
  • [33] X-RAY ABSORPTION-SPECTROSCOPY OF SMALL MOLECULES, FREE AND ADSORBED ON SURFACES
    SOMERS, J
    TOPICS IN APPLIED PHYSICS, 1992, 69 : 177 - 201
  • [34] Surface analysis of partially crystalline and amorphous poly(ethylene terephthalate) samples by X-ray absorption spectroscopy (NEXAFS)
    Lippitz, A
    Friedrich, JF
    Unger, WES
    Schertel, A
    Woll, C
    POLYMER, 1996, 37 (14) : 3151 - 3155
  • [35] Electronic Structure of Individual Hybrid Colloid Particles Studied by Near-Edge X-ray Absorption Fine Structure (NEXAFS) Spectroscopy in the X-ray Microscope
    Henzler, Katja
    Guttmann, Peter
    Lu, Yan
    Polzer, Frank
    Schneider, Gerd
    Ballauff, Matthias
    NANO LETTERS, 2013, 13 (02) : 824 - 828
  • [36] The significance of fluorescence in transmission X-ray absorption spectroscopy and X-ray absorption fine structure
    Sier, Daniel
    Ekanayake, Ruwini Supeshala Kumari
    Chantler, Christopher Thomas
    X-RAY SPECTROMETRY, 2022, 51 (01) : 91 - 100
  • [37] Physical information in polarized x-ray absorption spectroscopy and x-ray photoemission spectroscopy (abstract)
    Thole, Bernard Theodoor
    Journal of Applied Physics, 1994, 75 (10 pt 2A)
  • [38] Adding dynamic to electron spectroscopy: Evolution of active catalyst surfaces studied by in-situ X-ray photoelectron spectroscopy and soft X-ray absorption spectroscopy
    Haevecker, Michael
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 244
  • [39] An X-ray diffraction and X-ray absorption spectroscopy joint study of neuroglobin
    Arcovito, Alessandro
    Moschetti, Tommaso
    D'Angelo, Paola
    Mancini, Giordano
    Vallone, Beatrice
    Brunori, Maurizio
    Della Longa, Stefano
    ARCHIVES OF BIOCHEMISTRY AND BIOPHYSICS, 2008, 475 (01) : 7 - 13
  • [40] X-RAY PHOTOELECTRON-SPECTROSCOPY OF SURFACES
    DELGASS, WN
    BULLETIN OF THE AMERICAN PHYSICAL SOCIETY, 1974, 19 (03): : 292 - 292
12345