Oxovanadium complexes with multidentate ligands

被引:0
|
作者
Khurram Shahzad Munawar
Saqib Ali
Muhammad Iqbal
Allah Nawaz Khan
机构
[1] Quaid-i-Azam University,Department of Chemistry
[2] Capital Hospital,Department of Biochemistry
[3] CDA,undefined
关键词
VOSO; oxovanadium complexes; geometries; multidentate ligands;
D O I
10.1134/S2079978013040018
中图分类号
学科分类号
摘要
Vanadium has ability to coordinate with multidentate ligands in different geometries to produce variety of complexes. Usually the reactions are carried out by refluxing the methanolic solution of oxovanadium salt (VOSO4) with the ligands. Vanadyl sulphate can easily exchange its sulphate group with organic ligands. Sometimes solvent molecules are also attached with the complexes. Vanadyl oxygen usually occupies the axial position. The syntheses and geometries, and selective crystal structures of these complexes are discussed.
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页码:304 / 322
页数:18
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