Fluorescence Study on Miscibility in Poly(N-vinylcarbazole)/Poly(oxyethylene) Blends

被引：0
|
作者：
Fumihiko Ishizaki
Shinjiro Machida
Kazuyuki Horie
机构：
[1] Graduate School of Engineering,Department of Chemistry and Biotechnology
[2] The University of Tokyo,undefined
来源：
Polymer Journal | 2000年 / 32卷
关键词：
Poly(; -vinylcarbazole); Poly(oxyethylene); Blends; Partial Overlap Excimer; Full Overlap Excimer; Miscibility; Energy Migration;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Some miscibility between poly(N-vinylcarbazole) (PVCz) and poly(oxyethylene) (PEO) has been found for the first time by means of the two kinds of excimer emission of 8.0–100 wt% PVCz in the PVCz/PEO blends. Interchain energy migration to a full-overlap excimer site in the blends is suggested on the basis of time-resolved fluorescence spectra. The emission ratio between partial-overlap and full-overlap excimers shows PVCz concentration dependence similar to that of film transparency, reflecting chain aggregation in PVCz/PEO blends. Schematic diagrams of microscopic phase-separation structure of the blends for various PVCz contents are also proposed.
引用
收藏
页码：62 / 66
页数：4
相关论文
共 50 条
  • [31] CHEMICAL MODIFICATION OF POLY(N-VINYLCARBAZOLE)
    PIELICHOWSKI, J
    MORAWIEC, E
    JOURNAL OF APPLIED POLYMER SCIENCE, 1976, 20 (07) : 1803 - 1812
  • [32] A synthesis technology of poly(N-vinylcarbazole)
    Dai, Ya-Jie
    Dong, Wei
    Zhang, Wen-Long
    Wang, Xuan
    Zhao, Hong
    Bai, Yong-Ping
    Cailiao Kexue yu Gongyi/Material Science and Technology, 2009, 17 (05): : 632 - 635
  • [33] PHOTOGENERATION PROCESSES IN POLY (N-VINYLCARBAZOLE)
    PFISTER, G
    WILLIAMS, DJ
    JOURNAL OF CHEMICAL PHYSICS, 1974, 61 (06): : 2416 - 2426
  • [34] Synthesis of uniform hollow poly(N-vinylcarbazole) and liquid crystal/poly(N-vinylcarbazole) core/shell nanoparticles
    Jung, Yuri
    Choi, Jongwan
    Oh, Jin-Woo
    Kim, Nakjoong
    SYNTHETIC METALS, 2013, 163 : 24 - 28
  • [35] Fluorescence from poly(N-vinylcarbazole) in uniaxially stretched polymer films
    Ikawa, T
    Shiga, T
    Okada, A
    JOURNAL OF APPLIED POLYMER SCIENCE, 1997, 66 (08) : 1569 - 1573
  • [36] TEMPERATURE-DEPENDENCE OF THE INTENSITY OF FLUORESCENCE OF POLY(N-VINYLCARBAZOLE) FILMS
    KLIMOVIC, MTJ
    CHUDACEK, I
    POLYMER BULLETIN, 1983, 9 (1-3) : 52 - 59
  • [37] FLUORESCENCE QUENCHING AND SINGLET ENERGY MIGRATION IN POLY(2-VINYLNAPHTHALENE) AND POLY(N-VINYLCARBAZOLE)
    WEBBER, SE
    AVOTSAVOTINS, PE
    DEUMIE, M
    MACROMOLECULES, 1981, 14 (01) : 105 - 110
  • [38] Photoluminescence and electroluminescence properties of coumarin-urea/poly(N-vinylcarbazole) blends
    Zheng, HP
    Zhang, RF
    Wu, F
    Tian, WJ
    Shen, JC
    SYNTHETIC METALS, 1999, 100 (03) : 291 - 295
  • [39] A conducting nanocomposite of poly(N-vinylcarbazole) with buckminsterfullerene
    Biswas, M
    Ray, SS
    SYNTHETIC METALS, 2001, 123 (01) : 135 - 139
  • [40] EXCIMER DYNAMICS IN POLY(N-VINYLCARBAZOLE) FILMS
    MASUHARA, H
    TAMAI, N
    IKEDA, N
    MATAGA, N
    ITAYA, A
    OKAMOTO, K
    KUSABAYASHI, S
    CHEMICAL PHYSICS LETTERS, 1982, 91 (02) : 113 - 116
12345