Oxidative desulfurization of diesel fuels in the presence of crown ethers and transition metal peroxo complexes

被引：0
|
作者：
E. V. Rakhmanov
Dan Jinyuan
O. A. Fedorova
A. V. Tarakanova
A. V. Anisimov
机构：
[1] Moscow State University,
来源：
Theoretical Foundations of Chemical Engineering | 2012年 / 46卷
关键词：
oxidation; desulfurization; diesel fuel; crown ether; peroxo complex;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The catalytic activity of crown ethers and their complexes with transition metal cations in diesel fuel desulfurization has been investigated. With dibenzo-18-crown-6 in combination with NbCl5, the total sulfur content of the fuel can be reduced by a factor of 2 or larger. The effects of the reaction temperature, nature of metal and crown ether, and sorbent acidity on the residual sulfur content are reported. Methods of separation of oxidized compounds, namely adsorption chromatography and extraction are compared in terms of desulfurization efficiency. The latter method is demonstrated to be preferable.
引用
收藏
页码：552 / 555
页数：3
相关论文
共 50 条
  • [41] Oxidative Desulfurization of Jet and Diesel Fuels Using Hydroperoxide Generated in Situ by Catalytic Air Oxidation
    Sundararaman, Ramanathan
    Ma, Xiaoliang
    Song, Chunshan
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2010, 49 (12) : 5561 - 5568
  • [42] MoOx nanoclusters decorated on spinel-type transition metal oxide porous nanosheets for aerobic oxidative desulfurization of fuels
    Liu, Zijia
    Zhang, Yingnan
    Bai, Jiabao
    Yang, Huawei
    Yang, Lixia
    Bai, Liangjiu
    Wei, Donglei
    Wang, Wenxiang
    Liang, Ying
    Chen, Hou
    FUEL, 2023, 334
  • [43] ALIPHATIC CH BOND HYDROXYLATIONS IN TRANSITION-METAL PEROXO COMPLEXES
    KITAJIMA, N
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 207 : 278 - INOR
  • [44] Mechanism of olefin epoxidation with transition metal peroxo complexes: DFT study
    Yudanov, I. V.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2007, 48 (Suppl 1) : S111 - S124
  • [45] STUDY OF A NEW TYPE OF TRANSITION-METAL PEROXO COMPLEXES AS OXIDANTS
    SALAPALA, J
    ROUE, J
    GUERCHAIS, JE
    JOURNAL OF MOLECULAR CATALYSIS, 1980, 7 (01): : 141 - 148
  • [46] Mechanism of olefin epoxidation with transition metal peroxo complexes: DFT study
    I. V. Yudanov
    Journal of Structural Chemistry, 2007, 48 : S111 - S124
  • [47] Life cycle assessment of environmental impacts associated with oxidative desulfurization of diesel fuels catalyzed by metal-free reduced graphene oxide*
    Lin, Shichun
    Ng, Sue-Faye
    Ong, Wee-Jun
    ENVIRONMENTAL POLLUTION, 2021, 288
  • [48] Indenyl crown ethers: Heterotopic ligands with π- and σ-faces and the synthesis of cymantrene and cobaltocene crown ethers and their alkaline metal ion complexes
    Plenio, Herbert
    Burth, Dirk
    Organometallics, 1996, 15 (04):
  • [49] REACTIONS OF AMINES AND RELATED SPECIES WITH TRANSITION-METAL PEROXO COMPLEXES
    CENINI, S
    PORTA, F
    PIZZOTTI, M
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 296 (1-2) : 291 - 300
  • [50] The Oxidative Desulfurization of HDS Diesel: Using Aldehyde and Molecular Oxygen in the Presence of Cobalt Catalysts
    Rao, T. V.
    Krishna, P. M.
    Paul, D.
    Nautiyal, B. R.
    Kumar, J.
    Sharma, Y. K.
    Nanoti, S. M.
    Sain, B.
    Garg, M. O.
    PETROLEUM SCIENCE AND TECHNOLOGY, 2011, 29 (06) : 626 - 632
12345