A study of the molecular and crystal structure of the coordination metallopolymer {[Co(C11H20N4O2)(H2O)3], [Co(H2O)6](NO3)4}n

被引：0

作者：

V. V. Dotsenko

E. E. Netreba

机构：

[1] Kuban State University,

来源：

Journal of Structural Chemistry | 2015年 / 56卷

关键词：

cobalt(II); distorted octahedron; spirocarbone; coordination polymer; structure; single-crystal XRD;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Single crystal X-ray diffraction is used to determine the crystal structure of the coordination metallopolymer {[Co(C11H20N4O2)(H2O)3], [Co(H2O)6](NO3)4}n (I), which is prepared by reacting Co(NO3)2·6H2O with 4,4,10,10-tetramethyl-1,3,7,9-tetraazospiro[5.5]undecane-2,8-dione monohydrate (C11H20N4O2·H2O) in acetone. The crystallographic parameters of I: triclinic structure, sp. gr. P2/c, a = 15.2449(6) Å, b = 9.2600(3) Å, c = 18.4205(6) Å, β = 103.321(4)°, V = 2530.42(15) Å3, Z = 2, C22H64N14O34Co3, dx = 1.635 g/cm3, T = 298 K, R1 = 0.051 for 3757 F0 > 4σ(F), S = 1.03 to 2θmax = 58.08°. A crystal of I contains octahedral complex cations [Co(H2O)6]2+, nitrate anions, and metallopolymer chains of the composition [Co(C11H10N4O2)(H2O)3]n2n+, in which the molecules of the organic ligand are interconnected by binuclear cobalt complexes.

引用

页码：304 / 309

页数：5

共 50 条

[21] Dielectric properties of Co(CO3)(H2O)2(C3H4N2)2 and [Co(C3H3N2)2]n
Swiatek-Tran, B.
Kolodziej, H. A.
Vogt, A.
Tran, V. H.
RSC ADVANCES, 2015, 5 (13): : 9539 - 9545
[22] ASSOCIATION OF N-2 WITH NH4+ AND H3O+(H2O)1, H3O+(H2O)2, H3O+(H2O)3
GHENO, F
FITAIRE, M
JOURNAL OF CHEMICAL PHYSICS, 1987, 87 (02): : 953 - 958
[23] CRYSTAL-STRUCTURE OF [AS(C6H5)4]2[RE3CL11(H2O)].H2O
JUNG, B
MEYER, G
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1990, 45 (07): : 1097 - 1099
[24] Crystal structure of triaqua(4,4′-azopyridine-κ2N,N′)(2,3-naphthalenedicarboxylato)cobalt(II) monohydrate, Co(H2O)3(C12O4H6)(C10N4H8) • H2O
Liu, Chun-Sen
Hu, Min
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2010, 225 (02): : 267 - 269
[25] Synthesis and crystal structure of [Ni(H2O)6][Ni(H2O)2(C4H2O4)]•4H2O
Zheng, YQ
Kong, ZP
JOURNAL OF COORDINATION CHEMISTRY, 2003, 56 (11) : 967 - 973
[26] Crystal structure and properties of coordination polymer:: {[Co(μ-4, 4′-bipy) (4,4′-bipy)2(H2O)2] • (4, 4′-bipy) • (H2O)4 • (OH)3 • (Me)4N}n
Jin, J
Niu, SY
Yang, ZZ
Yang, GD
Ye, L
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2004, 25 (03): : 418 - 420
[27] Synthesis and crystal structures of [Al(H2O)6](SO4)NO3•2H2O and [Al(H2O)6](SO4)Cl•H2O
Svensson, Fredric G.
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2021, 77 : 58 - +
[28] THE CRYSTAL-STRUCTURES OF 3 ADDUCTS OF LANTHANIDE NITRATES, WATER AND 4,4'-BIPYRIDYL - [LA2(H2O)7(NO3)6].4C10H8N2,[HO(H2O)3(NO3)3].2C10H8N2 AND [Y(H2O)3(NO3)3].2C10H8N2
WEAKLEY, TJR
INORGANICA CHIMICA ACTA-ARTICLES, 1982, 63 (02): : 161 - 168
[29] THE CRYSTAL-STRUCTURE OF HEXAAQUOCOBALT(II) DINITRATE BIS-(HEXAMETHYLENETETRAMINE) TETRAHYDRATE (CO(H2O)6)(NO3)2, 2C6H12N4, 4H2O
VIOSSAT, B
KHODADAD, P
RODIER, N
BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE PARTIE I-PHYSICOCHIMIE DES SYSTEMES LIQUIDES ELECTROCHIMIE CATALYSE GENIE CHIMIQUE, 1981, (1-2): : 69 - 73
[30] Syntheses, Molecular Structures and Supramolecular Assembly in Three Mixed-Ligands Cobalt(II) Complexes trans-[Co(HOOC-(C6H4)-COO)2(H2O)2(C3N2H4)2], cis-mer-[Co(C8H4O4)(H2O)2(C3H4N2)3], H2O and trans-[Co(H2O)2(C3N2H2)4][OOC-C4H2S]-COO]
Fadila, Balegroune
Aouaouche, Benkanoun
Slimane, Dahaoui
Smail, Triki
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2016, 72 : S235 - S235

← 1 2 3 4 5 →