A-site substitution-controlled dielectric dispersion in lead-free sodium bismuth titanate

被引:0
|
作者
M. Raghavender
G. S. Kumar
G. Prasad
机构
[1] Osmania University,Materials Research Laboratory, Department of Physics
来源
Pramana | 2009年 / 72卷
关键词
Na; Bi; TiO; lead-free ferroelectrics; dielectric dispersion; impedance; relaxation times; 77.80.e; 77.22; 77.22.gm; 77.80;
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学科分类号
摘要
Effect of doping in Na0.5Bi0.5TiO3 (NBT) with Ce3+ and Sm3+ at the A-site on dielectric behaviour, impedance and conductivity is being reported. Na0.5Bi0.5−xAxTiO3 samples (A being Ce and Sm) are studied with varying values of x. For Na0.5Bi0.5−xCexTiO3 samples x is 0.001, 0.005 and 0.007 and for Na0.5Bi0.5−xSmxTiO3 samples x is 0.05, 0.1 and 0.15. Dielectric constant and loss are studied in the frequency range 10 kHz to 1 MHz and in the temperature range 30–650°C. Impedance and electric modulus studies are undertaken. The relaxations observed in the samples are non-Debye and activation energies for relaxation and conduction are evaluated.
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页码:999 / 1009
页数:10
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