Binding of gold(iii) with silver(i) dipropyldithiocarbamate: supramolecular self-assembly (role of secondary Au…S and Ag…S bonds) and thermal behavior of the ionic-polymer complex ([Au(S2CNPr2)2][AgCl2])n

被引：0
|
作者：
E. V. Korneeva
A. I. Smolentsev
O. N. Antzutkin
A. V. Ivanov
机构：
[1] Far-Eastern Branch of the Russian Academy of Sciences,Institute of Geology and Nature Management
[2] Siberian Branch of the Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry
[3] Novosibirsk State University,undefined
[4] Luleå University of Technology,undefined
[5] University of Warwick,undefined
来源：
Russian Chemical Bulletin | 2019年 / 68卷
关键词：
dialkyldithiocarbamates; binary complexes; noble metals; gold silver compounds; supramolecular self-assembly; secondary interactions; C MAS NMR spectroscopy; thermal behavior;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The double ionic-polymer complex ([Au(S2CNPr2)2][AgCl2])n (1) was prepared as an individual fixation form of gold(III) from NaCl solutions with silver(I) dipropyldithiocarbamate and was characterized by single-crystal X-ray diffraction and 13C magic-angle spinning (MAS) NMR spectroscopy. The structure of 1 comprises two nonequivalent centrosymmetric complex cations [Au(S2CNPr2)2]+ (A and B) and the discrete linear anion [AgCl2]–. Gold(III) cations are linked by pairs of unsymmetrical secondary Au…S bonds to form linear supramolecular chains (…A…B…)n. Neighboring cations are additionally linked by [AgCl2]– anions via secondary Ag…S and Cl…S bonds, the anions being involved in the overall stabilization of the supramolecular structure. The cation–anion interactions lead to a distortion of the linear configuration of the [AgCl2]– anion. The character of thermolysis of 1 accompanied by quantitative regeneration of bound Au and Ag was established by simultaneous thermal analysis.
引用
收藏
页码：40 / 47
页数：7
相关论文
共 50 条
  • [41] Chemisorption of the [AuCl4]- anion by cadmium cyclo-pentamethylenedithiocarbamate and the resulting bound-gold(III) species: The supramolecular structure and thermal behavior of the polynuclear complexes ([Au{S2CN(CH2)5}2]2[CdCl4]) n and ([Au{S2CN(CH2)5}Cl2]) n
    Rodina, T. A.
    Ivanov, A. V.
    Loseva, O. V.
    Zaeva, A. S.
    Gerasimenko, A. V.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2013, 58 (03) : 338 - 349
  • [42] Chemisorption of the [AuCl4]− anion by cadmium cyclo-pentamethylenedithiocarbamate and the resulting bound-gold(III) species: The supramolecular structure and thermal behavior of the polynuclear complexes ([Au{S2CN(CH2)5}2]2[CdCl4])n and ([Au{S2CN(CH2)5}Cl2])n
    T. A. Rodina
    A. V. Ivanov
    O. V. Loseva
    A. S. Zaeva
    A. V. Gerasimenko
    Russian Journal of Inorganic Chemistry, 2013, 58 : 338 - 349
  • [43] Formation of the ionic gold(III) complex [Au3{S2CN(CH2)4O}6][Au2Cl8][AuCl4] in chemisorption systems [M{S2CN(CH2)4O}2] n -[AuCl4]-/2 M HCl (M = Cd, Zn): Supramolecular structure and thermal behavior
    Rodina, T. A.
    Loseva, O. V.
    Ivanov, A. V.
    Gerasimenko, A. V.
    Sergienko, V. I.
    Zaeva, A. S.
    Korneeva, E. V.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2013, 39 (10) : 694 - 703
  • [44] Formation of the ionic gold(III) complex [Au3{S2CN(CH2)4O}6][Au2Cl8][AuCl4] in chemisorption systems [M{S2CN(CH2)4O}2]n-[AuCl4]−/2 M HCl (M = Cd, Zn): Supramolecular structure and thermal behavior
    T. A. Rodina
    O. V. Loseva
    A. V. Ivanov
    A. V. Gerasimenko
    V. I. Sergienko
    A. S. Zaeva
    E. V. Korneeva
    Russian Journal of Coordination Chemistry, 2013, 39 : 694 - 703
  • [45] Fixation mode of gold(III) in [Cd{S2CN(CH2)4O}2] n -[AuCl4]-/2 M HCl chemisorption system: Preparation, supramolecular self-organization and thermal behavior of the heteropolynuclear complex ([Au{S2CN(CH2)4O}2]2[CdCl4] • H2O) n
    Rodina, T. A.
    Loseva, O. V.
    Gerasimenko, A. V.
    Ivanov, A. V.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2013, 58 (09) : 1104 - 1111
  • [46] Supramolecular self-assembly in triphenyllead(IV) dimethylphosphinodithioate, 1x[Ph3PbS2PMe2], a chain polymer built through intermolecular Pb•••S secondary bonds
    Edelmann, FT
    Haiduc, I
    Silvestru, C
    Schmidt, HG
    Noltemeyer, M
    POLYHEDRON, 1998, 17 (11-12) : 2043 - 2047
  • [47] Polymeric complexes ([Au{S2CN(CH2)4O}2]2[ZnCl4] · 2H2O)n and ([Au{S2CN(CH2)4O}2]Cl · 2H2O)n as individual gold(III)-binding forms in the [Zn2{S2CN(CH2)4O}4]n-[AuCl4]−/2M HCl chemisorption system: Supramolecular self-organization and thermal behavior
    A. V. Ivanov
    T. A. Rodina
    O. V. Loseva
    Russian Journal of Coordination Chemistry, 2014, 40 : 875 - 884
  • [48] Polymeric complexes ([Au{S2CN(CH2)4O}2]2[ZnCl4] • 2H2O) n and ([Au{S2CN(CH2)4O}2]Cl • 2H2O) n as individual gold(III)-binding forms in the [Zn2{S2CN(CH2)4O}4] n -[AuCl4]-/2M HCl chemisorption system: Supramolecular self-organization and thermal behavior
    Ivanov, A. V.
    Rodina, T. A.
    Loseva, O. V.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2014, 40 (12) : 875 - 884
  • [49] Polynuclear Complexes of Gold(III) of the Composition ([Au(S2CNR2)2][AuCl4])n (R = C4H9, R2 = (CH2)5): Synthesis, Supramolecular Structures, and Thermal Behavior
    Ivanov, A. V.
    Zinkin, S. A.
    Gerasimenko, A. V.
    Sergienko, V. I.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2011, 37 (06) : 452 - 459
  • [50] Polynuclear complexes of gold(III) of the composition ([Au(S2CNR2)2][AuCl4])n (R = C4H9, R2 = (CH2)5): Synthesis, supramolecular structures, and thermal behavior
    A. V. Ivanov
    S. A. Zinkin
    A. V. Gerasimenko
    V. I. Sergienko
    Russian Journal of Coordination Chemistry, 2011, 37
12345