Parameters of luminescence and the local structure of Eu3+ centers in fluorogermanate glasses

被引:0
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作者
S. A. Nemov
A. V. Marchenko
P. P. Seregin
机构
[1] St. Petersburg State Polytechnical University,
[2] Herzen Russian State Pedagogical University,undefined
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关键词
Isomer Shift; Glass Physic; Luminescence Band; Calcium Magnesium; Europium Atom;
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摘要
The influence of the chemical nature of the local environment of Eu3+ ions on the parameters of luminescence of these centers in glasses of the (BaGeO3)1 − x − y(Al2O3)x(0.45CaF2 · 0.55MgF2)y (x = 0.25, y = 0; x = 0.17, y = 0.17; x = 0.15, y = 0.22; x = 0.07, y = 37.00; x = 0, y = 0.45) system is investigated. The oxidation state of europium atoms and the degree of homogeneity of their local environment in the glasses are determined using 151Eu Mössbauer spectroscopy.
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页码:47 / 49
页数:2
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