Unexpected Transformations of Alkyldiallylamines in the KOH-DMSO System

被引:0
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作者
G. K. Musorin
机构
[1] Russian Academy of Sciences,Favorskii Irkutsk Institute of Chemistry, Siberian Division
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关键词
Reaction Temperature; Product Ratio; Unexpected Transformation; Triallylamine;
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摘要
Triallylamine in the KOH-DMSO system readily isomerizes into tri(1-propenyl)amine. Alkyldi-allylamines in the same system give 1-ethyl-3-methylcyclohexane along with alkyldi(1-propenyl)amine. Theeffect of quantity of base, reaction temperature on product ratio was studied. A route of 1-ethyl-3-methyl-cyclohexane formation was proposed.
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页码:1576 / 1577
页数:1
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