Photoinduced Electron Transfer Reactions of Hexarhenium(III) Cluster: Oxidative Quenching of [Re6S8Cl6]4− Emission by Electron Acceptors

被引：0
|
作者：
Noboru Kitamura
Natsuki Kobayashi
Shoji Ishizaka
Takashi Yoshimura
Haeng-Boo Kim
Yoichi Sasaki
机构：
[1] Hokkaido University,Department of Chemistry, Faculty of Science
[2] Hiroshima University,Department of Chemistry, Graduate School of Science
[3] Osaka University,Radioisotope Research Center
[4] Ibaraki University,Department of Chemistry, Faculty of Science
来源：
Journal of Cluster Science | 2015年 / 26卷
关键词：
Hexarhenium(III) cluster; Photoinduced electron transfer; Charge separation;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The photoredox ability of a hexarhenium(III) cluster, [Re6(μ3-S)8Cl6]4−, in acetonitrile was examined on the basis of the emission quenching experiments of the cluster by a series of neutral organic electron acceptors (A). The photoinduced electron transfer quenching rate constants and the relevant activation parameters demonstrated that the hexarhenium(III) cluster acted as a useful photoredox sensitizer towards various A and the system gave a high charge separation yield owing to electrostatic repulsion between the product ions: [Re6(μ3-S)8Cl6]3− and A−. These results were proved explicitly by nanosecond transient absorption spectroscopy.
引用
收藏
页码：211 / 221
页数：10
相关论文
共 50 条
  • [41] SOLUTION CHEMISTRY OF CHALCOHALIDE HEXANUCLEAR RHENIUM CLUSTER MONOANIONS - SUBSTITUTION-REACTIONS AND STRUCTURAL AND LSIMS CHARACTERIZATION OF THE HETEROSUBSTITUTED CLUSTER DIANIONS, (N-BU(4)N)(2)[RE(6)Q(5)ECL(8)](Q=S,E=S,SE Q=SE,E=S,SE,TE)
    URIEL, S
    BOUBEKEUR, K
    BATAIL, P
    ORDUNA, J
    CANADELL, E
    INORGANIC CHEMISTRY, 1995, 34 (21) : 5307 - 5313
  • [42] Controlled synthesis and luminescence properties of trans-[Re6S8(CN)4(OH)2-n( H2O)]n-4 octahedral rhenium(III) cluster units (n=0, 1 or 2)
    Ledneva, Alexandra Yu.
    Brylev, Konstantin A.
    Smolentsev, Anton I.
    Mironov, Yuri V.
    Molard, Yann
    Cordier, Stephane
    Kitamura, Noboru
    Naumov, Nikolay G.
    POLYHEDRON, 2014, 67 : 351 - 359
  • [43] ELECTRON-TRANSFER SERIES OF MOFE3S4 DOUBLE-CUBANE CLUSTERS - ELECTRONIC-PROPERTIES OF COMPONENTS AND THE STRUCTURE OF [(C2H5)4N]5[MO2FE6S8(SC6H5)9]
    CHRISTOU, G
    MASCHARAK, PK
    ARMSTRONG, WH
    PAPAEFTHYMIOU, GC
    FRANKEL, RB
    HOLM, RH
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (10) : 2820 - 2831
  • [44] A family of octahedral rhenium cluster complexes trans-[{Re6Q8}(PPh3)4X2] (Q = S or Se, X = Cl, Br or I): Preparation and halide-dependent luminescence properties
    Ivanov, Anton A.
    Shestopalov, Michael A.
    Brylev, Konstantin A.
    Khlestkin, Vadim K.
    Mironov, Yuri V.
    POLYHEDRON, 2014, 81 : 634 - 638
  • [45] Hydrogen bonding in two ionic complexes built from octahedral rhenium(III) chalcocyanohydroxo cluster anions and tris(ethylenediamine)nickel(II) cations, [Ni(en)3]2[Re6S8(CN)4(OH)2]•5.5H2O and [Ni(en)3]2[Re6Se8(CN)4(OH)2]•10H2O
    Smolentsev, Anton I.
    Ermolaev, Andrey V.
    Mironov, Yuri V.
    JOURNAL OF MOLECULAR STRUCTURE, 2012, 1014 : 57 - 62
  • [46] Oxygen atom transfer reactions from dioxygen to phosphines via a bridging sulfur dioxide in a trinuclear cluster complex of rhenium, [(Ph3P)2N][Re3(μ3-S)(μ-S)2(μ-SO2)Cl6(PMe2Ph)3]
    Saito, T
    Sunaga, T
    Sakai, N
    Nakamura, Y
    Yamamoto, S
    Iriuchijima, D
    Yoza, K
    INORGANIC CHEMISTRY, 2005, 44 (12) : 4427 - 4432
  • [47] Silicagel support mediated nonphotolytic cleavage of the rhenium-rhenium bond of [{NC5H4N=NC6H4(R)}(CO)3Re0]2.: Synthesis of the monomeric species ReI{NC5H4N=NC6H4(R)}(CO)3Cl, crystal structure, spectroscopic and electron-transfer properties
    Samanta, R
    Munshi, P
    Santra, BK
    Lokanath, NK
    Sridhar, MA
    Prasad, JS
    Lahiri, GK
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 579 (1-2) : 311 - 320
  • [48] First example of bidentate coordination of the octahedral rhenium(III) cluster anion to a 3d-transition metal ion: Assembly of 2D coordination network [{Cu(NH3)3}2{Re6S8(OH)4(μ-OH)2}]•8H2O
    Smolentsev, Anton I.
    Mironov, Yuri V.
    POLYHEDRON, 2013, 50 (01) : 490 - 494
  • [49] A new class of sulfur bridged ruthenium-molybdenum complexes, (L)2RuII(μ-S)2MoIV(OH) 2 [L=NC5H4N=NC6H4(R), R=H, o-Me/Cl, m-Me/Cl]. Synthesis, spectroscopic and electron-transfer properties
    Department of Chemistry, Indian Inst. Technol., Bombay, Powai, Mumbai-400076, India
    Polyhedron, 7 (995-1004):
  • [50] A new class of sulfur bridged ruthenium-molybdenum complexes, (L)2RuII(μ-S)2MoIV(OH)2 [L = NC5H4N=NC6H4(R), R = H, o-Me/Cl, m-Me/Cl].: Synthesis, spectroscopic and electron-transfer properties
    Samanta, R
    Munshi, P
    Santra, BK
    Lahiri, GK
    POLYHEDRON, 1999, 18 (07) : 995 - 1004
12345