Electrochemically Induced Phosphorus-Methyl Bond Formation Involving the Complex [Co(Ph2PCH2P(Ph)2PPPPP(Ph)2CH2PPh2)]BF4

被引：0
|
作者：
Kuchkaev, Airat M. [1 ,2 ]
Kuchkaev, Aidar M. [1 ,2 ]
Sukhov, A. V. [1 ,2 ]
Ivanov, A. S. [2 ]
Khayarov, Kh. R. [2 ]
Dobrynin, A. B. [1 ,3 ]
Sinyashin, O. G. [1 ]
Yakhvarov, D. G. [1 ,2 ]
机构：
[1] RAS, Arbuzov Inst Organ & Phys Chem, FRC Kazan Sci Ctr, Kazan, Russia
[2] Kazan Volga Reg Fed Univ, Kazan, Russia
[3] Kazan Natl Res Tech Univ, Kazan, Russia
来源：
RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 2024年 / 60卷 / 02期
基金：
俄罗斯科学基金会;
关键词：
cobalt complexes; white phosphorus; methylation; polyphosphorus ligands; cyclic voltammetry; preparative electrolysis; mediated reduction; MEDIATED ACTIVATION; CRYSTAL-STRUCTURE; COBALT COMPLEX; HALOGEN;
D O I：
10.1134/S1023193524020046
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
The electrochemical properties of [Co(Ph2PCH2P(Ph)(2)PPPPP(Ph)(2)CH2PPh2)]BF4 complex have been studied by the method of cyclic voltammetry. The electrochemical methylation of this complex have been cunducted in the presence of iodomethane which has led to the formation of phosphonium salt-methylene bis(methyldiphenylphosphonium) diiodide as final product. It was found, that this reaction proceeds with the breakage of the P-P bonds in polyphosphorus ligand and with the formation of new P-C bonds.
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页码：129 / 134
页数：6
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