Equilibrium of acyl transfer between pyridine N-oxides and their acylonium salts

被引：0
|
作者：
V. I. Rubachenko
G. Schroeder
K. Yu. Chotii
V. V. Kovalenko
A. N. Red’ko
B. Lenska
机构：
[1] National Academy of Sciences of Ukraine,Litvinenko Instituteof Physical Organic and Coal Fuel Chemistry
[2] Adam Mickiewicz University,undefined
来源：
Russian Journal of General Chemistry | 2008年 / 78卷
关键词：
Equilibrium Constant; General Chemistry; Reaction Series; Tetraphenylborate; Acyl Transfer;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Transfer of acyl groups from N-acyloxypyridinium salts to pyridine N-oxides in acetonitrile was studied. The equilibrium constants of acyl exchange were determined. These quantities vary in the range covering eight orders of magnitude, depending on the structure of the reagents, and are independent of the structure of the acyl group.
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页码：1241 / 1246
页数：5
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