Zn(II) and Cu(II) Complexes with the Cluster-based Ligand [Re6(μ3-Se)8(PEt3)5(PTA)](SbF6)2 (PTA = 1,3,5-Triaza-7-phosphaadamantane)

被引：0
|
作者：
Xiaoyan Tu
Gary S. Nichol
Zhiping Zheng
机构：
[1] The University of Arizona,Department of Chemistry
来源：
Journal of Cluster Science | 2009年 / 20卷
关键词：
Rhenium chalcogenide clusters; Water-soluble ligand; Coordination; Crystal structure;
D O I：
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摘要：
Zn(II) and Cu(II) complexes of the cluster-based ligand [Re6(μ3-Se)8(PEt3)5(PTA)](SbF6)2 (PTA = 1,3,5-triaza-7-phosphaadamantane), {Zn[Re6(μ3-Se)8(PEt3)5(PTA)](NO3)3}(SbF6) (1) and {Cu[Re6(μ3-Se)8(PEt3)5(PTA)](NO3)3}(SbF6) (2), were prepared and structurally characterized. They are the first N-coordinated Zn(II) and Cu(II) complexes wherein the PTA ligand displays an interesting and less-frequently observed P, N-coordination mode.
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