Zn(II) and Cu(II) Complexes with the Cluster-based Ligand [Re6(μ3-Se)8(PEt3)5(PTA)](SbF6)2 (PTA = 1,3,5-Triaza-7-phosphaadamantane)

被引：0

作者：

Xiaoyan Tu

Gary S. Nichol

Zhiping Zheng

机构：

[1] The University of Arizona,Department of Chemistry

来源：

Journal of Cluster Science | 2009年 / 20卷

关键词：

Rhenium chalcogenide clusters; Water-soluble ligand; Coordination; Crystal structure;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Zn(II) and Cu(II) complexes of the cluster-based ligand [Re6(μ3-Se)8(PEt3)5(PTA)](SbF6)2 (PTA = 1,3,5-triaza-7-phosphaadamantane), {Zn[Re6(μ3-Se)8(PEt3)5(PTA)](NO3)3}(SbF6) (1) and {Cu[Re6(μ3-Se)8(PEt3)5(PTA)](NO3)3}(SbF6) (2), were prepared and structurally characterized. They are the first N-coordinated Zn(II) and Cu(II) complexes wherein the PTA ligand displays an interesting and less-frequently observed P, N-coordination mode.

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[1] Zn(II) and Cu(II) Complexes with the Cluster-based Ligand [Re6(μ 3-Se)8(PEt3)5(PTA)](SbF6)2 (PTA=1,3,5-Triaza-7-phosphaadamantane)
Tu, Xiaoyan
Nichol, Gary S.
Zheng, Zhiping
[J]. JOURNAL OF CLUSTER SCIENCE, 2009, 20 (01) : 93 - 103
[2] Molecular and polymeric Hg(II) complexes with a PTA (1,3,5-triaza-7-phosphaadamantane) complex of the [Re6(μ3-Se)8]2+ core-containing cluster as ligand
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Truong, Huong
Nichol, Gary S.
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[J]. INORGANICA CHIMICA ACTA, 2010, 363 (15) : 4189 - 4196
[3] Complexes of the [Re6(μ3-Se)8] 2+ core-containing clusters with the water-soluble 1,3,5-triaza-7-phosphaadamantane (PTA) ligand: Unexpected ligand protonation and related studies
Department of Chemistry, University of Arizona, Tucson, AZ 85721, United States
不详
[J]. Dalton Trans., 2008, 43 (6030-6038):
[4] Complexes of the [Re6(μ3-Se)8]2+ core-containing clusters with the water-soluble 1,3,5-triaza-7-phosphaadamantane (PTA) ligand: unexpected ligand protonation and related studies
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