Thermal and spectroscopic investigation on N,N-dimethylbenzylamine based cyclopalladated compounds containing isonicotinamide

被引：0
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作者：
Alessandra Stevanato
Antonio E. Mauro
Adelino V. G. Netto
机构：
[1] UNESP,Instituto de Química de Araraquara
来源：
Journal of Thermal Analysis and Calorimetry | 2009年 / 97卷
关键词：
Palladium(II); Isonicotinamide; Spectroscopy; Thermal behavior;
D O I：
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学科分类号：
摘要：
Synthesis, spectroscopic characterization and thermal analysis of the [Pd(dmba)(Cl)(iso)] (1), [Pd(dmba)(NCO)(iso)] (2), [Pd(dmba)(N3)(iso)] (3) and [Pd(dmba)(Br)(iso)] (4) (dmba = N,N′-dimethylbenzylamine; iso = isonicotinamide) compounds are described in this work. The complexes were investigated by infrared spectroscopy (IR), differential thermal analysis (DTA) and thermogravimetry (TG) and the residues of the thermal decomposition were identified as Pdo by X-ray powder diffraction. The thermal stability order of the complexes varied as [Pd(dmba)(Cl)(iso)] (1) > [Pd(dmba)(Br)(iso)] (4) > [Pd(dmba)(NCO)(iso)] (2) > [Pd(dmba)(N3)(iso)] (3).
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