Pentacarbonyl(N,N-dimethylbenzylamine)-tungsten

被引：3
|
作者：
Mahmud, T
Iqbal, J
Irshad, M
Elsegood, MRJ
McKee, V [1 ]
机构：
[1] Univ Loughborough, Dept Chem, Loughborough LE11 3TU, Leics, England
[2] Univ Punjab, Inst Chem, Lahore 54590, Pakistan
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2005年 / 61卷
关键词：
D O I：
10.1107/S1600536805025560
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [W(C9H13N)(CO)(5)], was prepared by irradiation of W( CO) 6 in tetrahydrofuran in the presence of N,N-dimethylbenzylamine. The geometry at the W atom is approximately octahedral, with the cis bond angles in the range 86.3 (3)-95.6 (2)degrees. The bond to the tertiary amine is long [2.371 (5) angstrom] and, as might be expected, the bond to the trans carbonyl is quite short [W-C = 1.964 (7) angstrom]. The remaining W-CO bonds lie in the range 2.033 (6)-2.049 (6) angstrom. Similar bonding patterns have been observed in related W(CO) (5)(amine) complexes.
引用
收藏
页码：M1789 / M1791
页数：3
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