13C and1H NMR spectroscopic characterization of titanium(IV) alkylperoxo complexes Ti(OOtBu)n(OiPr)4−n with n=1, 2, 3, 4

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作者
D. E. Babushkin
E. P. Talsi
机构
[1] Boreskov Institute of Catalysis,
关键词
Mechanism; oxidation; alkylperoxo complexes of titanium(IV); C NMR spectroscopy;
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摘要
Using13C and1H NMR spectroscopy, titanium(IV) alkylperoxo complexes Ti(OOtBu)n(OiPr)4−n with n=1, 2, 3 and 4 were characterized in the reaction of Ti(OiPr)4 withtBuOOH in CH2Cl2 and CDCl3.
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页码:359 / 364
页数:5
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