The synthesis and crystal structure of (4E)-5(3-chlorophenyl)-N-(4-chlorophenyl)-2-diazo3-oxopent-4-enoic acid amide

被引：0
|
作者：
Dong Heng-Shan
Wang Dong-Dong
Jin Chi-Qiong
机构：
[1] Lanzhou University,State Key Laboratory of Applied Organic Chemistry, Institute of Organic Chemistry, College of Chemistry and Chemical Engineering
来源：
Journal of Chemical Crystallography | 2005年 / 35卷
关键词：
Crystal structure; diazodicarbonyl compound; 2-diazo-3-oxopent-4-enoic acid amide; synthesis; ethyl (acetoketal)acetate; (2-methyl-[1,3]dioxolan-2-yl)acetic acid ethyl ester;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
(4E)-5-(3-Chlorophenyl)-N-(4-chlorophenyl)-2-diazo-3-oxopent-4-enoic acid amide (5) was synthesized from p-chloroaniline to N-(4-chlorophenyl)-2-diazo-3-oxo-butyramide (4) with 3-chlorobenzaldehyde. The yielded product 5 was investigated with X-ray crystallographic, NMR, MS, and IR techniques. Compound 5 (C17H11Cl2N3O2, Formula wt = 360.19), crystallizes in the monoclinic space group P21/c with unit cell parameters a = 10.516(2), b = 17.996(4), c = 8.902(2) Å, α = 90.00, β = 105.36(3), γ = 90.00∘. V = 1624.5(6) Å3, Z = 4, Dx = 1.473 Mg m−3. The final R was 0.0511.
引用
收藏
页码：897 / 901
页数：4
相关论文
共 50 条
  • [31] 4-Chloro-N-(3-chlorophenyl)benzenesulfonamide
    Shakuntala, K.
    Foro, Sabine
    Gowda, B. Thimme
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O1017 - U1744
  • [32] 4-Chloro-N-(3-chlorophenyl)benzamide
    Nayak, Susanta K.
    Reddy, M. Kishore
    Row, T. N. Guru
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O2434 - +
  • [33] The Crystal Structure of N-[(2E)-3-(4-Chlorophenyl)prop-2-en-1-yl]-4-methoxy-N-methylbenzenesulfonamide
    Benedetta Carrozzini
    Benny Danilo Belviso
    Claudio Bruno
    Maria Maddalena Cavalluzzi
    Angelo Lovece
    Giovanni Lentini
    Rocco Caliandro
    Journal of Chemical Crystallography, 2019, 49 : 87 - 91
  • [34] The Crystal Structure of N-[(2E)-3-(4-Chlorophenyl)prop-2-en-1-yl]-4-methoxy-N-methylbenzenesulfonamide
    Carrozzini, Benedetta
    Belviso, Benny Danilo
    Bruno, Claudio
    Cavalluzzi, Maria Maddalena
    Lovece, Angelo
    Lentini, Giovanni
    Caliandro, Rocco
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2019, 49 (02) : 87 - 91
  • [35] Crystal structure of N '-[(E)-(4-chlorophenyl)(phenyl)methylidene]-4-methyl-benzenesulfonohydrazide
    Balaji, J.
    Prabu, S.
    Xavier, J. J. F.
    Srinivasan, P.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : O45 - +
  • [36] Synthesis and Crystal Structure of (E)-[1-Ferrocenyl-2-(4-Chlorophenyl) ethylene]
    QIAN Ying
    SUN Yue-Ming
    LIU Ju-Zheng(Department of Chemistry
    HU Chun-Hua
    ZHENG Pei-Ju(Research Center of Analysis and Measurement
    结构化学, 1997, (04) : 315 - 319
  • [37] 2-(4-Chlorophenyl)-N-(3,4-difluorophenyl)acetamide
    Praveen, A. S.
    Yathirajan, H. S.
    Jasinski, Jerry P.
    Keeley, Amanda C.
    Narayana, B.
    Sarojini, B. K.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O996 - +
  • [38] N-(4-Chlorophenyl)-4-(2-oxocyclopentyl)butyramide
    Yu, Lin-Tao
    Wei, Jiang-Tao
    Zhou, Xiang-Ge
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O162 - U2681
  • [39] N-(4-Chlorophenyl)quinolin-2-amine
    Hasan, Zainal Abidin
    Abdullah, Zanariah
    Tajuddin, Hairul Anuar
    Ng, Seik Weng
    Tiekink, Edward R. T.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O3175 - U1773
  • [40] N-(4-Chlorophenyl)-2,2-diphenylacetamide
    Fun, Hoong-Kun
    Loh, Wan-Sin
    Nayak, Prakash S.
    Narayana, B.
    Sarojini, B. K.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : 02556 - +
12345