Trisubstituted 1,3,5-triazines. 5. Reaction of 2,4,6-tris[di(tert-butoxycarbonyl)nitromethyl]-1,3,5-triazine with nucleophiles

被引：0

作者：

Shastin, A.V. ^{[1
]}

Godovikova, T.I. ^{[2
]}

Korsunskii, B.L. ^{[2
]}

机构：

[1] Inst. for Prob. in Chemical Physics, Russian Academy of Sciences, Chemogolovka 142432, Russia

[2] N. D. Zelinsky Inst. of Organ. Chem., Moscow 117913, Russia

来源：

Chemistry of Heterocyclic Compounds | 2003年 / 39卷 / 05期

关键词：

2,4,6-tris[di(tert-butoxycarbonyl)nitromethyl]-1,3,5-triazine - Aliphatic amines - Di(tert-butoxycarbonyl)nitromethyl group - Diethylamines - Dimethylamines - Dimethylammonium - Morpholines - Nucleophilic reagent - Nucleophilic substitutions;

D O I：

10.1023/A:1025150216863

中图分类号：

学科分类号：

摘要：

The reaction of 2,4,6-tris[di(tert-butoxycarbonyl)nitromethyl]-1,3,5-triazine with ammonia, amines, and hydrazine has been studied. It was possible to substitute one of the di(tert-butoxycarbonyl)nitromethyl groups in this compound in the presence of ammonia, primary aliphatic amines, dimethylamine, and morpholine. The reaction with hydrazine leads to both mono- and disubstituted products. A double dealkoxylation occurs in the presence of diethylamine to give the bis(dimethylammonium) salt of 2,4-bis(tert-butoxycarbonylnitromethyl)-6-[di(tert-butoxycarbonyl)nitromethyl]-1,3,5-triazine.

引用

页码：624 / 631

页数：7

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