Trisubstituted 1,3,5-triazines. 5. Reaction of 2,4,6-tris[di(tert-butoxycarbonyl)nitromethyl]-1,3,5-triazine with nucleophiles

被引：0
|
作者：
Shastin, A.V. [1 ]
Godovikova, T.I. [2 ]
Korsunskii, B.L. [2 ]
机构：
[1] Inst. for Prob. in Chemical Physics, Russian Academy of Sciences, Chemogolovka 142432, Russia
[2] N. D. Zelinsky Inst. of Organ. Chem., Moscow 117913, Russia
来源：
Chemistry of Heterocyclic Compounds | 2003年 / 39卷 / 05期
关键词：
2,4,6-tris[di(tert-butoxycarbonyl)nitromethyl]-1,3,5-triazine - Aliphatic amines - Di(tert-butoxycarbonyl)nitromethyl group - Diethylamines - Dimethylamines - Dimethylammonium - Morpholines - Nucleophilic reagent - Nucleophilic substitutions;
D O I：
10.1023/A:1025150216863
中图分类号：
学科分类号：
摘要：
The reaction of 2,4,6-tris[di(tert-butoxycarbonyl)nitromethyl]-1,3,5-triazine with ammonia, amines, and hydrazine has been studied. It was possible to substitute one of the di(tert-butoxycarbonyl)nitromethyl groups in this compound in the presence of ammonia, primary aliphatic amines, dimethylamine, and morpholine. The reaction with hydrazine leads to both mono- and disubstituted products. A double dealkoxylation occurs in the presence of diethylamine to give the bis(dimethylammonium) salt of 2,4-bis(tert-butoxycarbonylnitromethyl)-6-[di(tert-butoxycarbonyl)nitromethyl]-1,3,5-triazine.
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页码：624 / 631
页数：7
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